caa a22 4500 463188268 CHVBK 20180406164900.0 cr unu---uuuuu 170326e20070401xx s 000 0 eng 10.1007/s10973-006-8134-9 doi (NATIONALLICENCE)springer-10.1007/s10973-006-8134-9 TG-MScharacterization of the reaction products of cadmium yellow and malachiteartist's pigments [Elektronische Daten] [R. White, P. Thomas, M. Philips, R. Wuhrer, J. Guerbois] The deleterious interaction of some traditional sulphide artists pigments and copper ions results in the formation of black copper sulphides, in particular, covellite (CuS), and, hence, the discolouration of valuable artworks. In this paper the interaction of malachite, a source of copper(II) ions, with the pigment cadmium yellow, a sulphide pigment comprising of a solid solution of cadmium and zinc sulphides, is investigated by XRD and TG-MS. XRD showed the presence of the copper sulphide and cadmium carbonate phases, produced by a simple ion exchange mechanism. TG-MS showed the complexity of the range of metastable phases produced. The identification of these phases, however, requires further work. Springer-Verlag, 2007 cadmium yellow nationallicence malachite nationallicence thermogravimetric analysis nationallicence White R. Microstructural Analysis Unit, University of Technology Sydney, Broadway, PO Box 123, NSW 2007, Sydney, Australia aut Thomas P. Dept. Chemistry, Materials and Forensic Science, University of Technology Sydney, Broadway, PO Box 123, NSW 2007, Sydney, Australia aut Philips M. Microstructural Analysis Unit, University of Technology Sydney, Broadway, PO Box 123, NSW 2007, Sydney, Australia aut Wuhrer R. Microstructural Analysis Unit, University of Technology Sydney, Broadway, PO Box 123, NSW 2007, Sydney, Australia aut Guerbois J. Dept. Chemistry, Materials and Forensic Science, University of Technology Sydney, Broadway, PO Box 123, NSW 2007, Sydney, Australia aut Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 88/1(2007-04-01), 181-184 1388-6150 88:1<181 2007 88 10973 https://doi.org/10.1007/s10973-006-8134-9 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-8134-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- White R. Microstructural Analysis Unit, University of Technology Sydney, Broadway, PO Box 123, NSW 2007, Sydney, Australia aut NATIONALLICENCE 700 1- Thomas P. Dept. Chemistry, Materials and Forensic Science, University of Technology Sydney, Broadway, PO Box 123, NSW 2007, Sydney, Australia aut NATIONALLICENCE 700 1- Philips M. Microstructural Analysis Unit, University of Technology Sydney, Broadway, PO Box 123, NSW 2007, Sydney, Australia aut NATIONALLICENCE 700 1- Wuhrer R. Microstructural Analysis Unit, University of Technology Sydney, Broadway, PO Box 123, NSW 2007, Sydney, Australia aut NATIONALLICENCE 700 1- Guerbois J. Dept. Chemistry, Materials and Forensic Science, University of Technology Sydney, Broadway, PO Box 123, NSW 2007, Sydney, Australia aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 88/1(2007-04-01), 181-184 1388-6150 88:1<181 2007 88 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer