caa a22 4500 463188322 CHVBK 20180406164900.0 cr unu---uuuuu 170326e20070601xx s 000 0 eng 10.1007/s10973-006-8087-z doi (NATIONALLICENCE)springer-10.1007/s10973-006-8087-z Applicability of the Kissinger equation in thermal analysis [Elektronische Daten] Revisited [P. Budrugeac, E. Segal] For the most common kinetic models used in heterogeneous reactions, the dependencies on x m = E/RT m (E is the activation energy, T m is the temperature corresponding to maximum process rate, R is the gas constant) on the relative errors (e%) in the determination of the activation energy from the slope of the Kissinger straight line ln(β / T m 2 ) vs. 1/T m (β is the heating rate) are evaluated. It is pointed out that, for x m≥10.7 and all kinetic models, ∣e%∣≤5%. Some possible cases exhibiting high values of ∣e%∣, which can be higher than 10%, are put in evidence and discussed. Springer Science+Business Media, LLC., 2007 Kissinger equation nationallicence non-isothermal kinetics nationallicence Budrugeac P. INCDIE-ICPE-CA — National Institute for Research and Development in Electrical Engineering, 313 Splaiul Unirii, 030138, Bucharest, Romania aut Segal E. Department of Physical Chemistry, University of Bucharest, 4-12 Bd. Elisabeta, 7034, Bucharest, Romania aut Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 88/3(2007-06-01), 703-707 1388-6150 88:3<703 2007 88 10973 https://doi.org/10.1007/s10973-006-8087-z text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-8087-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Budrugeac P. INCDIE-ICPE-CA — National Institute for Research and Development in Electrical Engineering, 313 Splaiul Unirii, 030138, Bucharest, Romania aut NATIONALLICENCE 700 1- Segal E. Department of Physical Chemistry, University of Bucharest, 4-12 Bd. Elisabeta, 7034, Bucharest, Romania aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 88/3(2007-06-01), 703-707 1388-6150 88:3<703 2007 88 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer