caa a22 4500 463188349 CHVBK 20180406164900.0 cr unu---uuuuu 170326e20070601xx s 000 0 eng 10.1007/s10973-005-7466-1 doi (NATIONALLICENCE)springer-10.1007/s10973-005-7466-1 Non-isothermal crystallization of MaterBi-Z/clay nanocomposites [Elektronische Daten] [C. Pérez, V. Alvarez, P. Stefani, A. Vázquez] Non-isothermal crystallization of MaterBi-Z (starch-polycaprolactone blend) and its nanocomposites with different clay contents (0, 2.5 and 5 mass%) was studied. The experimental data show that clay can be act both as nucleating or retarding agent depend on the clay content. Kinetic parameters obtained by using a non-linear regression method, i.e., Kamal's model and Dietz's modification, were able to describe the non-isothermal crystallization behavior of the studied materials. A full model that takes into account the induction and growth of the crystal during cooling under non-isothermal conditions was used to obtain a continuous cooling transformation diagrams. Springer Science+Business Media, LLC., 2007 biodegradable polymers nationallicence clay nanocomposites nationallicence kinetic models nationallicence MaterBi-Z nationallicence non-isothermal crystallization nationallicence polycaprolactone nationallicence starch nationallicence Pérez C. Research Institute of Material Science and Technology (INTEMA), National Research Council (CONICET), Engineering Faculty, Mar del Plata University, Juan B. Justo 4302, 7600, Mar del Plata, Argentina aut Alvarez V. Research Institute of Material Science and Technology (INTEMA), National Research Council (CONICET), Engineering Faculty, Mar del Plata University, Juan B. Justo 4302, 7600, Mar del Plata, Argentina aut Stefani P. Research Institute of Material Science and Technology (INTEMA), National Research Council (CONICET), Engineering Faculty, Mar del Plata University, Juan B. Justo 4302, 7600, Mar del Plata, Argentina aut Vázquez A. Research Institute of Material Science and Technology (INTEMA), National Research Council (CONICET), Engineering Faculty, Mar del Plata University, Juan B. Justo 4302, 7600, Mar del Plata, Argentina aut Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 88/3(2007-06-01), 825-832 1388-6150 88:3<825 2007 88 10973 https://doi.org/10.1007/s10973-005-7466-1 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-005-7466-1 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Pérez C. Research Institute of Material Science and Technology (INTEMA), National Research Council (CONICET), Engineering Faculty, Mar del Plata University, Juan B. Justo 4302, 7600, Mar del Plata, Argentina aut NATIONALLICENCE 700 1- Alvarez V. Research Institute of Material Science and Technology (INTEMA), National Research Council (CONICET), Engineering Faculty, Mar del Plata University, Juan B. Justo 4302, 7600, Mar del Plata, Argentina aut NATIONALLICENCE 700 1- Stefani P. Research Institute of Material Science and Technology (INTEMA), National Research Council (CONICET), Engineering Faculty, Mar del Plata University, Juan B. Justo 4302, 7600, Mar del Plata, Argentina aut NATIONALLICENCE 700 1- Vázquez A. Research Institute of Material Science and Technology (INTEMA), National Research Council (CONICET), Engineering Faculty, Mar del Plata University, Juan B. Justo 4302, 7600, Mar del Plata, Argentina aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 88/3(2007-06-01), 825-832 1388-6150 88:3<825 2007 88 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer