caa a22 4500 463188365 CHVBK 20180406164900.0 cr unu---uuuuu 170326e20070601xx s 000 0 eng 10.1007/s10973-005-7452-7 doi (NATIONALLICENCE)springer-10.1007/s10973-005-7452-7 Binary mixtures based on polycaprolactone and cellulose derivatives [Elektronische Daten] Thermal degradation and pyrolysis [A. Jiménez, Roxana Ruseckaite] Pyrolytic process has a promising potential for the environmentally friendly upgrading of lignocellulosic and plastic waste. Thermogravimetry and pyrolysis-gas chromatography-mass spectrometry (Py-GC/MS) were used to get information about the reactive decomposition of PCL in binary mixtures with microcrystalline cellulose (MC) or sisal fibres (SF). Preliminary thermogravimetric investigation showed that biomass is thermally degraded at lower temperatures than PCL and this process has a predominant influence on the thermal behaviour of the mixtures. Discrepancies between the experimental and predicted TG/DTG profiles were considered as a measurement of the extent of interactions occurring on co-pyrolysis. It was found that reactivity of PCL was slightly increased in PCL-SF binary mixtures. Evolution of acidic products from cellulose and hemicelluloses decomposition may promote PCL degradation in binary mixtures with SF. It seems that the co-pyrolysis process could have potential for the environmentally friendly transformation of biocomposites. Springer Science+Business Media, LLC., 2007 cellulose derivatives nationallicence mass spectrometry nationallicence polycaprolactone nationallicence pyrolysis nationallicence thermal analysis nationallicence Jiménez A. Department of Analytical Chemistry, Nutrition and Food Sciences, University of Alicante, P.O. Box 99, 03080, Alicante, Spain aut Ruseckaite Roxana Research Institute of Material Science and Technology (INTEMA), University of Mar del Plata, Juan B. Justo 4302, 7600, Mar del Plata, Argentina aut Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 88/3(2007-06-01), 851-856 1388-6150 88:3<851 2007 88 10973 https://doi.org/10.1007/s10973-005-7452-7 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-005-7452-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Jiménez A. Department of Analytical Chemistry, Nutrition and Food Sciences, University of Alicante, P.O. Box 99, 03080, Alicante, Spain aut NATIONALLICENCE 700 1- Ruseckaite Roxana Research Institute of Material Science and Technology (INTEMA), University of Mar del Plata, Juan B. Justo 4302, 7600, Mar del Plata, Argentina aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 88/3(2007-06-01), 851-856 1388-6150 88:3<851 2007 88 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer