caa a22 4500 463188489 CHVBK 20180406164900.0 cr unu---uuuuu 170326e20070601xx s 000 0 eng 10.1007/s10973-006-8020-5 doi (NATIONALLICENCE)springer-10.1007/s10973-006-8020-5 Kinetic of decomposition of some complexes under non-isothermal conditions [Elektronische Daten] [Gabriela Vlase, T. Vlase, Ramona Tudose, Otilia Costişor, N. Doca] Kinetics of thermal decomposition of three structurally similar complexes Co2Cu(C2O4)3 (R-diam)2, where R is ethyl, 1,2-propyl or 1,3-propyl, was studied under non-isothermal conditions and nitrogen dynamic atmosphere at heating rates of 5, 7, 10, 12 and 15 K min−1. For data processing the Flynn-Wall-Ozawa and a modified non-parametric kinetic methods were used. By both methods the activation energy are in the range of 97-102 kJ mol−1. The formal kinetic is r=kα(1−α)2. Also a compensation effect between lnA and E was evidenced. The kinetic analysis lead to the conclusion of an identic decomposition mechanism by a single step process. Springer Science+Business Media, LLC., 2007 non-isothermal kinetics nationallicence thermal decomposition nationallicence three-nuclear complexes nationallicence Vlase Gabriela Research Center for Thermal Analysis in Environmental Problems, West University of Timişoara, Str. Pestalozzi No. 16, 300115, Timişoara, Romania aut Vlase T. Research Center for Thermal Analysis in Environmental Problems, West University of Timişoara, Str. Pestalozzi No. 16, 300115, Timişoara, Romania aut Tudose Ramona Institute of Chemistry Timişoara, B-dul M. Viteazul, No. 24, Timişoara, Romania aut Costişor Otilia Institute of Chemistry Timişoara, B-dul M. Viteazul, No. 24, Timişoara, Romania aut Doca N. Research Center for Thermal Analysis in Environmental Problems, West University of Timişoara, Str. Pestalozzi No. 16, 300115, Timişoara, Romania aut Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 88/3(2007-06-01), 637-640 1388-6150 88:3<637 2007 88 10973 https://doi.org/10.1007/s10973-006-8020-5 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-8020-5 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Vlase Gabriela Research Center for Thermal Analysis in Environmental Problems, West University of Timişoara, Str. Pestalozzi No. 16, 300115, Timişoara, Romania aut NATIONALLICENCE 700 1- Vlase T. Research Center for Thermal Analysis in Environmental Problems, West University of Timişoara, Str. Pestalozzi No. 16, 300115, Timişoara, Romania aut NATIONALLICENCE 700 1- Tudose Ramona Institute of Chemistry Timişoara, B-dul M. Viteazul, No. 24, Timişoara, Romania aut NATIONALLICENCE 700 1- Costişor Otilia Institute of Chemistry Timişoara, B-dul M. Viteazul, No. 24, Timişoara, Romania aut NATIONALLICENCE 700 1- Doca N. Research Center for Thermal Analysis in Environmental Problems, West University of Timişoara, Str. Pestalozzi No. 16, 300115, Timişoara, Romania aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 88/3(2007-06-01), 637-640 1388-6150 88:3<637 2007 88 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer