caa a22 4500 463188713 CHVBK 20180406164901.0 cr unu---uuuuu 170326e20070601xx s 000 0 eng 10.1007/s10973-006-7552-z doi (NATIONALLICENCE)springer-10.1007/s10973-006-7552-z Effect of poly(bisphenol A acryloxyethyl phosphate) on the activation energy in thermal degradation of urethane acrylate [Elektronische Daten] [Z. Huang, W. Shi] Poly(bisphenol A acryloxyethyl phosphate) (BPAAEP) was blended in different ratios with a commercial urethane acrylate to obtain a series of UV curable flame-retardant resins. The thermal oxidative degradation mechanism of their cured films in air were studied by thermogravimetric analysis at several heating rates between 5 and 20°C min−1. The activation energies were determined using Kissinger method, Friedman method, Flynn-Wall method, Horowitz-Metzger method and Ozawa method. The results showed that the activation energies of the blends were lower than that of pure urethane acrylate at lower degree of degradation, whereas the higher activation energies were obtained at higher degree of degradation. Springer Science+Business Media, LLC., 2007 activation energy nationallicence degradation kinetics nationallicence flame-retardant nationallicence phosphate nationallicence UV curable nationallicence Huang Z. State Key Laboratory of Fire Science and Department of Polymer Science and Engineering, University of Science and Technology of China, 230026, Hefei, Anhui, P.R. China aut Shi W. State Key Laboratory of Fire Science and Department of Polymer Science and Engineering, University of Science and Technology of China, 230026, Hefei, Anhui, P.R. China aut Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 88/3(2007-06-01), 833-841 1388-6150 88:3<833 2007 88 10973 https://doi.org/10.1007/s10973-006-7552-z text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-7552-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Huang Z. State Key Laboratory of Fire Science and Department of Polymer Science and Engineering, University of Science and Technology of China, 230026, Hefei, Anhui, P.R. China aut NATIONALLICENCE 700 1- Shi W. State Key Laboratory of Fire Science and Department of Polymer Science and Engineering, University of Science and Technology of China, 230026, Hefei, Anhui, P.R. China aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 88/3(2007-06-01), 833-841 1388-6150 88:3<833 2007 88 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer