caa a22 4500 46318873X CHVBK 20180406164901.0 cr unu---uuuuu 170326e20070501xx s 000 0 eng 10.1007/s10973-006-8033-0 doi (NATIONALLICENCE)springer-10.1007/s10973-006-8033-0 Thermaland dynamic mechanical analysis of cross-linked poly(esterurethanes) [Elektronische Daten] [Lidia Jasińska, A. Balas, J. Haponiuk, G. Nowaczyk, S. Jurga] New cross-linked poly(esterurethanes) (PEU) based on unsaturated olygo(alkyleneester)diol (OAE), 4,4'-diphenylmethane diisocyanate (MDI) and styrene or methyl methacrylate as curing monomers were prepared. The synthesis of PEU was performed in two steps. In the first step OAE was obtained from adipic acid, maleic anhydride and ethylene glycol. In the second step a prepolymer was obtained in a reaction of OAE with different amounts of 4,4'-diphenylmethane diisocyanate followed by crosslinking using previously mentioned curing monomers. The influence of structure of the poly(esterurethanes) on thermal and dynamic mechanical properties is studied. Thermogravimetric analysis shows that cross-linked poly(esterurethanes) demonstrate high thermal stability. Moreover the dynamic mechanical thermal analysis shows that the presence of styrene cross-linking chains in polymers lead to the phase separation in cross-linked poly(esterurethanes). Springer-Verlag, 2007 dynamic-mechanical analysis nationallicence poly(esterurethanes) nationallicence thermal stability nationallicence Jasińska Lidia Faculty of Chemistry, Department of Polymer Technology, Gdańsk University of Technology, Narutowicza St 11/12, 80-952, Gdańsk, Poland aut Balas A. Faculty of Chemistry, Department of Polymer Technology, Gdańsk University of Technology, Narutowicza St 11/12, 80-952, Gdańsk, Poland aut Haponiuk J. Faculty of Chemistry, Department of Polymer Technology, Gdańsk University of Technology, Narutowicza St 11/12, 80-952, Gdańsk, Poland aut Nowaczyk G. Faculty of Physics, Department of Macromolecular Physics, Adam Mickiewicz University, Umultowska St 85, 61-614, Poznań, Poland aut Jurga S. Faculty of Physics, Department of Macromolecular Physics, Adam Mickiewicz University, Umultowska St 85, 61-614, Poznań, Poland aut Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 88/2(2007-05-01), 419-423 1388-6150 88:2<419 2007 88 10973 https://doi.org/10.1007/s10973-006-8033-0 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-8033-0 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Jasińska Lidia Faculty of Chemistry, Department of Polymer Technology, Gdańsk University of Technology, Narutowicza St 11/12, 80-952, Gdańsk, Poland aut NATIONALLICENCE 700 1- Balas A. Faculty of Chemistry, Department of Polymer Technology, Gdańsk University of Technology, Narutowicza St 11/12, 80-952, Gdańsk, Poland aut NATIONALLICENCE 700 1- Haponiuk J. Faculty of Chemistry, Department of Polymer Technology, Gdańsk University of Technology, Narutowicza St 11/12, 80-952, Gdańsk, Poland aut NATIONALLICENCE 700 1- Nowaczyk G. Faculty of Physics, Department of Macromolecular Physics, Adam Mickiewicz University, Umultowska St 85, 61-614, Poznań, Poland aut NATIONALLICENCE 700 1- Jurga S. Faculty of Physics, Department of Macromolecular Physics, Adam Mickiewicz University, Umultowska St 85, 61-614, Poznań, Poland aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 88/2(2007-05-01), 419-423 1388-6150 88:2<419 2007 88 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer