caa a22 4500 463188853 CHVBK 20180406164902.0 cr unu---uuuuu 170326e20070501xx s 000 0 eng 10.1007/s10973-007-8088-6 doi (NATIONALLICENCE)springer-10.1007/s10973-007-8088-6 Heteroleptictri- tert -butoxysilanethiolate complexesof manganese(II) [Elektronische Daten] Thermal studies [Anna Kropidłowska, M. Strankowski, Maria Gazda, Barbara Becker] The thermal behavior of Mn(II) silanethiolate series [Mn(SR)2L(MeOH)n], where R=SSi(OBut)3, L=heterocyclic nitrogen base and n=0, 1 or 2 has been comparatively investigated using differential scanning calorimetry (DSC), thermogravimetry (TG) and TG-infrared spectoscopy (IR) techniques. The TG curves indicate the differences in the thermal decomposition due to presence of distinct N-donor ligands and labile MeOH molecules coordinated to the central atom. The first step on the TG curves (60-110°C) corresponds to the elimination of alcohol from respective complexes. The main step (150-350°C) can be assigned to the decomposition of the complexes yielding Mn3O4 and silica as the main final products, identified by X-ray diffraction patterns. Springer-Verlag, 2007 manganese(II) complexes nationallicence metal thiolates nationallicence pyridine nationallicence silanethiolate nationallicence thermal analysis nationallicence Kropidłowska Anna Inorganic Chemistry Department, Gdańsk University of Technology, Narutowicza Str. 11/12, 80-952, Gdańsk, Poland aut Strankowski M. Polymer Technology Department, Chemical Faculty, Gdańsk University of Technology, Narutowicza Str. 11/12, 80-952, Gdańsk, Poland aut Gazda Maria Faculty of Applied Physics and Mathematics, Gdańsk University of Technology, Narutowicza Str. 11/12, 80-952, Gdańsk, Poland aut Becker Barbara Inorganic Chemistry Department, Gdańsk University of Technology, Narutowicza Str. 11/12, 80-952, Gdańsk, Poland aut Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 88/2(2007-05-01), 463-470 1388-6150 88:2<463 2007 88 10973 https://doi.org/10.1007/s10973-007-8088-6 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-007-8088-6 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kropidłowska Anna Inorganic Chemistry Department, Gdańsk University of Technology, Narutowicza Str. 11/12, 80-952, Gdańsk, Poland aut NATIONALLICENCE 700 1- Strankowski M. Polymer Technology Department, Chemical Faculty, Gdańsk University of Technology, Narutowicza Str. 11/12, 80-952, Gdańsk, Poland aut NATIONALLICENCE 700 1- Gazda Maria Faculty of Applied Physics and Mathematics, Gdańsk University of Technology, Narutowicza Str. 11/12, 80-952, Gdańsk, Poland aut NATIONALLICENCE 700 1- Becker Barbara Inorganic Chemistry Department, Gdańsk University of Technology, Narutowicza Str. 11/12, 80-952, Gdańsk, Poland aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 88/2(2007-05-01), 463-470 1388-6150 88:2<463 2007 88 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer