caa a22 4500 463188918 CHVBK 20180406164902.0 cr unu---uuuuu 170326e20070501xx s 000 0 eng 10.1007/s10973-006-8031-2 doi (NATIONALLICENCE)springer-10.1007/s10973-006-8031-2 Thermalstability of some new complexes bearing ligands with polymerizable groups [Elektronische Daten] [Mihaela Badea, Rodica Olar, Dana Marinescu, E. Segal, A. Rotaru] A series of new complexes with mixed ligands of the type M(4,4'-dipy)(C3H3O2)2(H2O)y ((1) M=Mn, y=2; (2) M=Ni, y=2; 4,4'-dipy: 4,4'-dipyridyl and C3H3O2 is acrylate anion) and respectively M2(4,4'-dipy)(C3H3O2)4(H2O)y ((3) M=Cu, y=0; (4) M=Zn, y=1). The modification evidenced in IR spectra was correlated with the presence of acrylate ion as unidentate in the case of complex (1) and as bidentate for others complexes. The electronic reflectance spectra showed the d-d transition for complex (1) and (2) characteristic for the octahedral surrounding while the spectrum for complex (3) have the characteristic pattern for square-pyramidal stereochemistry. The thermal behaviour steps were investigated. The thermal transformations are complex processes according to TG and DTG curves including dehydration, acrylate ion oxidative degradation and thermolysis process of aromatic amine. The final products of decomposition are the most stable metal oxides. Springer-Verlag, 2007 acrylate nationallicence complexes nationallicence 4,4'-dipyridyl nationallicence formate nationallicence thermal stability nationallicence Badea Mihaela Faculty of Chemistry, Department of Inorganic Chemistry, University of Bucharest, 90-92 Panduri St., 050663 Sector 5, Bucharest, Romania aut Olar Rodica Faculty of Chemistry, Department of Inorganic Chemistry, University of Bucharest, 90-92 Panduri St., 050663 Sector 5, Bucharest, Romania aut Marinescu Dana Faculty of Chemistry, Department of Inorganic Chemistry, University of Bucharest, 90-92 Panduri St., 050663 Sector 5, Bucharest, Romania aut Segal E. Faculty of Chemistry, Department of Physical Chemistry, University of Bucharest, 4-12 Elisabeta blvd, Bucharest, Romania aut Rotaru A. Faculty of Chemistry, Department of Physical Chemistry, University of Bucharest, 4-12 Elisabeta blvd, Bucharest, Romania aut Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 88/2(2007-05-01), 317-321 1388-6150 88:2<317 2007 88 10973 https://doi.org/10.1007/s10973-006-8031-2 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-8031-2 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Badea Mihaela Faculty of Chemistry, Department of Inorganic Chemistry, University of Bucharest, 90-92 Panduri St., 050663 Sector 5, Bucharest, Romania aut NATIONALLICENCE 700 1- Olar Rodica Faculty of Chemistry, Department of Inorganic Chemistry, University of Bucharest, 90-92 Panduri St., 050663 Sector 5, Bucharest, Romania aut NATIONALLICENCE 700 1- Marinescu Dana Faculty of Chemistry, Department of Inorganic Chemistry, University of Bucharest, 90-92 Panduri St., 050663 Sector 5, Bucharest, Romania aut NATIONALLICENCE 700 1- Segal E. Faculty of Chemistry, Department of Physical Chemistry, University of Bucharest, 4-12 Elisabeta blvd, Bucharest, Romania aut NATIONALLICENCE 700 1- Rotaru A. Faculty of Chemistry, Department of Physical Chemistry, University of Bucharest, 4-12 Elisabeta blvd, Bucharest, Romania aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 88/2(2007-05-01), 317-321 1388-6150 88:2<317 2007 88 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer