caa a22 4500 463188934 CHVBK 20180406164902.0 cr unu---uuuuu 170326e20070501xx s 000 0 eng 10.1007/s10973-006-8000-9 doi (NATIONALLICENCE)springer-10.1007/s10973-006-8000-9 Meltingand high-temperature solid state transitions in cobalt(II) halides [Elektronische Daten] [Alina Wojakowska, E. Krzyżak, Stanisława Plińska] Melting and high temperature solid-state transitions in CoCl2 and CoBr2 are widely discussed. On the basis of DSC and conductometric measurements it was found that melting process of CoCl2 is preceded by a solid-state transition appearing about 20 K below the melting point of CoCl2. Due to deconvolution of the thermograms, the enthalpy of fusion and that of solid-state transition were found to be 36.4 and 9.6 kJ mol-1, respectively. Melting points of CoCl2 and CoBr2 were established to be 999.0 and 949.7 K, respectively. Hitherto unknown enthalpy of fusion of CoBr2 was determined to be 27.2 kJ mol-1. A solid-state transition in CoBr2 at 650 K has been confirmed. Springer-Verlag, 2007 cobalt dibromide nationallicence cobalt dichloride nationallicence DSC nationallicence electrical conductivity nationallicence enthalpy of fusion nationallicence solid-state transition nationallicence Wojakowska Alina Department of Inorganic Chemistry, Laboratory of Thermal Analysis, Wrocław Medical University, ul. Szewska 38, 50 139, Wrocław, Poland aut Krzyżak E. Department of Inorganic Chemistry, Laboratory of Thermal Analysis, Wrocław Medical University, ul. Szewska 38, 50 139, Wrocław, Poland aut Plińska Stanisława Department of Inorganic Chemistry, Laboratory of Thermal Analysis, Wrocław Medical University, ul. Szewska 38, 50 139, Wrocław, Poland aut Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 88/2(2007-05-01), 525-530 1388-6150 88:2<525 2007 88 10973 https://doi.org/10.1007/s10973-006-8000-9 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-8000-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wojakowska Alina Department of Inorganic Chemistry, Laboratory of Thermal Analysis, Wrocław Medical University, ul. Szewska 38, 50 139, Wrocław, Poland aut NATIONALLICENCE 700 1- Krzyżak E. Department of Inorganic Chemistry, Laboratory of Thermal Analysis, Wrocław Medical University, ul. Szewska 38, 50 139, Wrocław, Poland aut NATIONALLICENCE 700 1- Plińska Stanisława Department of Inorganic Chemistry, Laboratory of Thermal Analysis, Wrocław Medical University, ul. Szewska 38, 50 139, Wrocław, Poland aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 88/2(2007-05-01), 525-530 1388-6150 88:2<525 2007 88 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer