caa a22 4500 46318906X CHVBK 20180406164903.0 cr unu---uuuuu 170326e20070501xx s 000 0 eng 10.1007/s10973-006-8228-4 doi (NATIONALLICENCE)springer-10.1007/s10973-006-8228-4 10.1007/s10973-006-8228-4 [Elektronische Daten] [L. Stoch, P. Stoch] The high-resolution transmission electron microscopy HRTEM study of the atomic scale mechanism of crystal structure organization within the amorphous polymeric structure of the model multicomponent glass TiO2-MgO-Al2O3-SiO2- in the glass transformation temperature range has been undertaken. In the glass transition (T g) temperature range, glass transforms from the solid of rigid amorphous structure into viscoelastic state of weakened chemical bonds. This is an example of nuclei formation and crystal growth in the polymeric amorphous structure of low atomic scale homogeneity due to middle range ordering. It has been demonstrated that in this case crystal structure formation proceeds by successive displacement and local ordering of atoms in the amorphous structure, like disorder-order transformation in crystalline solid bodies. As the consequence in the crystallization by parent structure reorganization mechanism, traditional model of glass crystallization as well as kinetic models of reactions in solid bodies according Avrami or others, are worthy to be revised. Springer-Verlag, 2007 crystallization nationallicence glass nationallicence nucleation nationallicence solids nationallicence structural self-organization nationallicence Stoch L. Institute of Glass and Ceramics, Warsaw, Poland aut Stoch P. Institut of Atomic Energy, Otwock/Swierk, Poland aut Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 88/2(2007-05-01), 577-582 1388-6150 88:2<577 2007 88 10973 https://doi.org/10.1007/s10973-006-8228-4 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-8228-4 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Stoch L. Institute of Glass and Ceramics, Warsaw, Poland aut NATIONALLICENCE 700 1- Stoch P. Institut of Atomic Energy, Otwock/Swierk, Poland aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 88/2(2007-05-01), 577-582 1388-6150 88:2<577 2007 88 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer