caa a22 4500 463189353 CHVBK 20180406164904.0 cr unu---uuuuu 170326e20071001xx s 000 0 eng 10.1007/s10973-006-7667-2 doi (NATIONALLICENCE)springer-10.1007/s10973-006-7667-2 Supermolecular structure variety of PMP membranes [Elektronische Daten] Thermogravimetric evidences [A. Wolnik, J. Borek, W. Sułkowski, M. Żarska, W. Zielińska-Danch, A. Danch] Thermogravimetry was applied in order to study the variety of the phase structure of poly(4-methyl-1-pentene) (PMP) membranes. The results gave indirect information about the morphology of the polymeric systems. DTG curves, recorded for the membranes including residual amount of solvent, exhibited three processes. The processes were interpreted as a removal of the solvent molecules occluded in different local structures: ‘real' amorphous; ‘semi-ordered' amorphous, crystalline. The location of the molecules in those structures was correlated with chain behaviours studied using dynamic mechanical analysis. The relaxation processes (αg, αc) were analysed with a special attention to the amount of occluded solvent molecules. Springer Science+Business Media, LLC., 2007 polymeric membranes nationallicence α-relaxation nationallicence supermolecular structure nationallicence thermogravimetry nationallicence Wolnik A. Inst. Chemii, Universytet Śląski, Szkolna 7, 40-007, Katowice, Poland aut Borek J. Inst. Chemii, Universytet Śląski, Szkolna 7, 40-007, Katowice, Poland aut Sułkowski W. Inst. Chemii, Universytet Śląski, Szkolna 7, 40-007, Katowice, Poland aut Żarska M. Inst. Nauki o Materiałach, Uniwersytet Śląski, Bankowa 12, 40-007, Katowice, Poland aut Zielińska-Danch W. Katedra Chemii Ogólnej i Analitycznej, Śląska Akademia Medyczna, Jagielońska 4, 41-200, Sosnowiec, Poland aut Danch A. Inst. Fizyki, Uniwersytet Śląski, Uniwersytecka 4, 40-007, Katowice, Poland aut Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/1(2007-10-01), 237-242 1388-6150 90:1<237 2007 90 10973 https://doi.org/10.1007/s10973-006-7667-2 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-7667-2 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wolnik A. Inst. Chemii, Universytet Śląski, Szkolna 7, 40-007, Katowice, Poland aut NATIONALLICENCE 700 1- Borek J. Inst. Chemii, Universytet Śląski, Szkolna 7, 40-007, Katowice, Poland aut NATIONALLICENCE 700 1- Sułkowski W. Inst. Chemii, Universytet Śląski, Szkolna 7, 40-007, Katowice, Poland aut NATIONALLICENCE 700 1- Żarska M. Inst. Nauki o Materiałach, Uniwersytet Śląski, Bankowa 12, 40-007, Katowice, Poland aut NATIONALLICENCE 700 1- Zielińska-Danch W. Katedra Chemii Ogólnej i Analitycznej, Śląska Akademia Medyczna, Jagielońska 4, 41-200, Sosnowiec, Poland aut NATIONALLICENCE 700 1- Danch A. Inst. Fizyki, Uniwersytet Śląski, Uniwersytecka 4, 40-007, Katowice, Poland aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/1(2007-10-01), 237-242 1388-6150 90:1<237 2007 90 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer