caa a22 4500 463189388 CHVBK 20180406164904.0 cr unu---uuuuu 170326e20071001xx s 000 0 eng 10.1007/s10973-006-7750-8 doi (NATIONALLICENCE)springer-10.1007/s10973-006-7750-8 Study of the isothermal free radical polymerization of some higher n -alkyl methacrylates [Elektronische Daten] [R. Radičević, D. Stoiljković, J. Budinski-Simendić] The free radical polymerizations of higher n-alkyl methacrylates were not investigated in detail until now. In this work, the courses of the isothermal free radical bulk polymerization of dodecyl, quatrodecyl and hexadecyl methacrylates were investigated by differential scanning calorimetry. The effects of the polymerization temperature and the alkyl group length in the esters on the monomer conversions during polymerization were studied. It was found that the polymerization rate vs. time curves have two maxima. The free radical polymerizations of above-mentioned monomers proceed with slightly expressed gel effect at the temperatures below 90°C, at initiator concentration 1 mass% in monomer. Springer Science+Business Media LLC, 2007 DSC nationallicence higher n-alkyl methacrylates nationallicence polymerization nationallicence Radičević R. Faculty of Technology, University of Novi Sad, Bulevar Cara Lazara 1, Novi Sad, Serbia aut Stoiljković D. Faculty of Technology, University of Novi Sad, Bulevar Cara Lazara 1, Novi Sad, Serbia aut Budinski-Simendić J. Faculty of Technology, University of Novi Sad, Bulevar Cara Lazara 1, Novi Sad, Serbia aut Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/1(2007-10-01), 243-247 1388-6150 90:1<243 2007 90 10973 https://doi.org/10.1007/s10973-006-7750-8 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-7750-8 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Radičević R. Faculty of Technology, University of Novi Sad, Bulevar Cara Lazara 1, Novi Sad, Serbia aut NATIONALLICENCE 700 1- Stoiljković D. Faculty of Technology, University of Novi Sad, Bulevar Cara Lazara 1, Novi Sad, Serbia aut NATIONALLICENCE 700 1- Budinski-Simendić J. Faculty of Technology, University of Novi Sad, Bulevar Cara Lazara 1, Novi Sad, Serbia aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/1(2007-10-01), 243-247 1388-6150 90:1<243 2007 90 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer