caa a22 4500 463189442 CHVBK 20180406164904.0 cr unu---uuuuu 170326e20071001xx s 000 0 eng 10.1007/s10973-006-7792-y doi (NATIONALLICENCE)springer-10.1007/s10973-006-7792-y Determination of micelle/water partition coefficients and associated thermodynamic data for dialkyl phthalate esters [Elektronische Daten] [Laura Waters, S. Leharne, J. Mitchell, J. Hanrahan] Micelle/water partition coefficients for three dialkyl phthalate esters — dimethyl phthalate ester (DMP), diethyl phthalate ester (DEP) and dipropyl phthalate ester (DPP) were obtained by micellar liquid chromatography (MLC). Experiments were conducted over a temperature range which led to calculation of a Gibbs free energy, enthalpy and entropy of transfer for the phthalate esters. In addition, small angle neutron scattering (SANS) experiments were conducted with no substantial change observed in micelle size before and after phthalate ester incorporation. Overall, a novel method for obtaining thermodynamic information, based on partitioning data, has been developed for dialkyl phthalate esters using micellar liquid chromatography. Springer Science+Business Media, LLC., 2007 micellar liquid chromatography (MLC) nationallicence micelle size nationallicence partitioning nationallicence phthalate esters nationallicence thermodynamics nationallicence Waters Laura Department of Chemical and Biological Sciences, University of Huddersfield, HD1 3DH, Queensgate, Huddersfield, UK aut Leharne S. School of Science, University of Greenwich, ME4 4TB, Chatham Maritime, Kent, UK aut Mitchell J. School of Science, University of Greenwich, ME4 4TB, Chatham Maritime, Kent, UK aut Hanrahan J. Department of Chemistry, Materials Section and Supercritical Fluid Centre, University College Cork, Cork, Ireland aut Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/1(2007-10-01), 283-288 1388-6150 90:1<283 2007 90 10973 https://doi.org/10.1007/s10973-006-7792-y text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-7792-y text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Waters Laura Department of Chemical and Biological Sciences, University of Huddersfield, HD1 3DH, Queensgate, Huddersfield, UK aut NATIONALLICENCE 700 1- Leharne S. School of Science, University of Greenwich, ME4 4TB, Chatham Maritime, Kent, UK aut NATIONALLICENCE 700 1- Mitchell J. School of Science, University of Greenwich, ME4 4TB, Chatham Maritime, Kent, UK aut NATIONALLICENCE 700 1- Hanrahan J. Department of Chemistry, Materials Section and Supercritical Fluid Centre, University College Cork, Cork, Ireland aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/1(2007-10-01), 283-288 1388-6150 90:1<283 2007 90 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer