caa a22 4500 463189809 CHVBK 20180406164905.0 cr unu---uuuuu 170326e20071201xx s 000 0 eng 10.1007/s10973-007-8559-9 doi (NATIONALLICENCE)springer-10.1007/s10973-007-8559-9 Matskevich N. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russia aut Enthalpy of formation of BaCe0.9In0.1O3−δ(s) [Elektronische Daten] [N. Matskevich] Enthalpy of formation of the perovskite-related oxide BaCe0.9In0.1O2.95 has been determined at 298.15 K by solution calorimetry. Solution enthalpies of barium cerate doped with indium and mixture of BaCl2, CeCl3, InCl3 in ratio 1:0.9:0.1 have been measured in 1 M HCl with 0.1 M KI. The standard formation enthalpy of BaCe0.9In0.1O2.95 has been calculated as −1611.7±2.6 kJ mol−1. Room-temperature stability of this compound has been assessed in terms of parent binary oxides. The formation enthalpy of barium cerate doped by indium from the mixture of binary oxides is Δox H 0 (298.15 K)=−36.2±3.4 kJ mol−1. Springer Science+Business Media, LLC., 2007 BaCeO3-based perovskite nationallicence solution calorimetry nationallicence thermodynamic stability nationallicence Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/3(2007-12-01), 955-958 1388-6150 90:3<955 2007 90 10973 https://doi.org/10.1007/s10973-007-8559-9 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-007-8559-9 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Matskevich N. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russia aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/3(2007-12-01), 955-958 1388-6150 90:3<955 2007 90 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer