caa a22 4500 463189817 CHVBK 20180406164905.0 cr unu---uuuuu 170326e20071201xx s 000 0 eng 10.1007/s10973-007-8430-z doi (NATIONALLICENCE)springer-10.1007/s10973-007-8430-z Transition metal complexes with pyrazole based ligands [Elektronische Daten] Part XXV. Deaquation of isostructural cobalt(II) and nickel(II) complexes with 3,5-dimethylpyrazole-1-carboxamidine [Katalin Mészáros Szécsényi, V. Leovac, R. Petković, Ž. Jaćimović, G. Pokol] The deaquation of two isostructural compounds of general formula [M(HL)2(H2O)2](NO3)2 (M=Co, Ni, HL=3,5-dimethyl-1H-pyrazole-1-carboxamidine) is discussed in the view of their crystal and molecular structure. The compounds contain the same number and type of hydrogen bonds of the adjacent nitrate ions, only in the opposite orientation. On the basis of their deaquation pattern such a small difference may be detected, i.e., methods of thermal analysis are sensitive enough to show very small structural differences. Springer Science+Business Media, LLC., 2007 Co(II) and Ni(II) complexes nationallicence crystal structure nationallicence deaquation nationallicence 3,5-dimethyl-1H-pyrazole-1-carboxamidine nationallicence Mészáros Szécsényi Katalin Faculty of Sciences, Department of Chemistry, University of Novi Sad, Trg D. Obradovića 3, 21000, Novi Sad, Serbia aut Leovac V. Faculty of Sciences, Department of Chemistry, University of Novi Sad, Trg D. Obradovića 3, 21000, Novi Sad, Serbia aut Petković R. Faculty of Sciences, Department of Chemistry, University of Novi Sad, Trg D. Obradovića 3, 21000, Novi Sad, Serbia aut Jaćimović Ž. Faculty of Metallurgy and Technology, Podgorica, Montenegro aut Pokol G. Institute for General and Analytical Chemistry, Budapest University of Technology and Economics, Szt. Gellért tér 4, 1521, Budapest, Hungary aut Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/3(2007-12-01), 899-902 1388-6150 90:3<899 2007 90 10973 https://doi.org/10.1007/s10973-007-8430-z text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-007-8430-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Mészáros Szécsényi Katalin Faculty of Sciences, Department of Chemistry, University of Novi Sad, Trg D. Obradovića 3, 21000, Novi Sad, Serbia aut NATIONALLICENCE 700 1- Leovac V. Faculty of Sciences, Department of Chemistry, University of Novi Sad, Trg D. Obradovića 3, 21000, Novi Sad, Serbia aut NATIONALLICENCE 700 1- Petković R. Faculty of Sciences, Department of Chemistry, University of Novi Sad, Trg D. Obradovića 3, 21000, Novi Sad, Serbia aut NATIONALLICENCE 700 1- Jaćimović Ž. Faculty of Metallurgy and Technology, Podgorica, Montenegro aut NATIONALLICENCE 700 1- Pokol G. Institute for General and Analytical Chemistry, Budapest University of Technology and Economics, Szt. Gellért tér 4, 1521, Budapest, Hungary aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/3(2007-12-01), 899-902 1388-6150 90:3<899 2007 90 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer