caa a22 4500 463189841 CHVBK 20180406164905.0 cr unu---uuuuu 170326e20071201xx s 000 0 eng 10.1007/s10973-007-8529-2 doi (NATIONALLICENCE)springer-10.1007/s10973-007-8529-2 Thermal decomposition of complexes of cadmium(II) and mercury(II) with triphenylphosphanes [Elektronische Daten] [R. Verma, L. Verma, A. Bhushan, B. Verma] A series of substituted triphenylphosphane complexes of the type CdL2X2 (L= triorthotolylphosphane or trimetatolylphosphane; X=Cl−, Br− or I−) and HgL2X2 (L=triphenylphosphane or triorthotolylphosphane) was prepared fresh. The thermal decomposition was carried out in air with heating rate programmed at 10°C min−1 and it revealed that the complexes with ortho derivative were less stable and the triphenylphosphane moiety leaves along with halogen in the first step. All the complexes were stable up to 210°C. However, the stability order of the tetrahedral complexes was X=Cl>Br. Values of n, E, lnA and ΔS # have been approximated and compared. Complexes having Br have higher E a, lnA and ΔS # values than that having Cl. Springer Science+Business Media, LLC., 2007 activation energy nationallicence cadmium(II) nationallicence complexes nationallicence entropy of activation nationallicence mercury(II) nationallicence non-isothermal solid state decomposition nationallicence trimetatolylphosphane nationallicence triorthotolylphosphane nationallicence triphenylphosphane nationallicence Verma R. University Department of Chemistry, Magadh University, 824234, Bodh Gaya, India aut Verma L. University Department of Chemistry, Magadh University, 824234, Bodh Gaya, India aut Bhushan A. University Department of Chemistry, Magadh University, 824234, Bodh Gaya, India aut Verma B. University Department of Chemistry, Magadh University, 824234, Bodh Gaya, India aut Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/3(2007-12-01), 725-729 1388-6150 90:3<725 2007 90 10973 https://doi.org/10.1007/s10973-007-8529-2 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-007-8529-2 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Verma R. University Department of Chemistry, Magadh University, 824234, Bodh Gaya, India aut NATIONALLICENCE 700 1- Verma L. University Department of Chemistry, Magadh University, 824234, Bodh Gaya, India aut NATIONALLICENCE 700 1- Bhushan A. University Department of Chemistry, Magadh University, 824234, Bodh Gaya, India aut NATIONALLICENCE 700 1- Verma B. University Department of Chemistry, Magadh University, 824234, Bodh Gaya, India aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/3(2007-12-01), 725-729 1388-6150 90:3<725 2007 90 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer