caa a22 4500 463190025 CHVBK 20180406164906.0 cr unu---uuuuu 170326e20071201xx s 000 0 eng 10.1007/s10973-006-8247-1 doi (NATIONALLICENCE)springer-10.1007/s10973-006-8247-1 Investigation of thermodynamic properties of magnesium chloride amines by HPDSC and TG [Elektronische Daten] For application in a high-lift high-temperature chemical heat pump [E. Bevers, H. Oonk, W. Haije, P. van Ekeren] The formation as well as the decomposition of magnesium chloride ammonia complexes was studied by high-pressure differential scanning calorimetry (HPDSC) and thermogravimetric analysis (TG). HPDSC runs were performed under constant ammonia pressure conditions to determine the transition temperatures and stability regions of the ammonia complexes. The TG technique has been employed to examine the stoichiometry of the complexes. The hexa-, di-and mono-ammines are proven to exist under our experimental conditions. The decomposition of the mono ammine to pure MgCl2 occurs most probably in two steps. Springer Science+Business Media, LLC., 2007 ammonia nationallicence chemical heat pump nationallicence DSC nationallicence magnesium chloride nationallicence stability diagram nationallicence TG nationallicence thermodynamic properties nationallicence Bevers E. Chemical Thermodynamics Group, Department of Chemistry, Utrecht University, Padualaan 8, 3584 CH, Utrecht, The Netherlands aut Oonk H. Chemical Thermodynamics Group, Department of Chemistry, Utrecht University, Padualaan 8, 3584 CH, Utrecht, The Netherlands aut Haije W. Energy Research Centre of the Netherlands, P.O. Box 1, 1755 ZG, Petten, The Netherlands aut van Ekeren P. TNO Defence, Security and Safety, BU3 Protection, Munitions and Weapons, Department Energetic Materials, P. O. Box 45, 2280 AA, Rijswijk, The Netherlands aut Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/3(2007-12-01), 923-929 1388-6150 90:3<923 2007 90 10973 https://doi.org/10.1007/s10973-006-8247-1 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-8247-1 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Bevers E. Chemical Thermodynamics Group, Department of Chemistry, Utrecht University, Padualaan 8, 3584 CH, Utrecht, The Netherlands aut NATIONALLICENCE 700 1- Oonk H. Chemical Thermodynamics Group, Department of Chemistry, Utrecht University, Padualaan 8, 3584 CH, Utrecht, The Netherlands aut NATIONALLICENCE 700 1- Haije W. Energy Research Centre of the Netherlands, P.O. Box 1, 1755 ZG, Petten, The Netherlands aut NATIONALLICENCE 700 1- van Ekeren P. TNO Defence, Security and Safety, BU3 Protection, Munitions and Weapons, Department Energetic Materials, P. O. Box 45, 2280 AA, Rijswijk, The Netherlands aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/3(2007-12-01), 923-929 1388-6150 90:3<923 2007 90 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer