caa a22 4500 46319019X CHVBK 20180406164906.0 cr unu---uuuuu 170326e20071101xx s 000 0 eng 10.1007/s10973-006-7608-0 doi (NATIONALLICENCE)springer-10.1007/s10973-006-7608-0 Thermal and spectral studies of palladium(II) complexes [Elektronische Daten] [A. Mishra, S. Mishra, N. Manav, N. Kaushik] Palladium(II) complexes of type [Pd(L)Cl2] [where L=2-aminopyridine-N-thiohydrazide (L1), (2-aminopyridine-N-thio)-1,3-propanediamine (L2), benzaldehyde 2-aminopyridine-N-thiohydrazone (L3) and salicylaldehyde-2-aminopyridine-N-thiohydrazone (L4)] have been synthesized. The thiohydrazide, thiodiamine and thiohydrazones can exist as thione-thiol tautomer and coordinate as a bidentate N-S ligand. The ligands found to act in bidentate fashion. The complexes have been characterized by elemental analysis, IR, mass, electronic, 1H NMR spectroscopic studies, and TG/DTA study. Antifungal studies of some complexes were also carried out. Various kinetic and thermodynamic parameters like order of reaction (n), activation energy (E a), apparent activation entropy (S # ) and heat of reaction (ΔH) have also been carried out for one complex. Springer Science+Business Media, LLC., 2007 characterization nationallicence palladium nationallicence synthesis nationallicence Mishra A. Department of Chemistry, University of Delhi, 110007, Delhi, India aut Mishra S. Department of Chemistry, University of the Free State, 9866, Free State, South Africa aut Manav N. Department of Chemistry, University of Delhi, 110007, Delhi, India aut Kaushik N. Department of Chemistry, University of Delhi, 110007, Delhi, India aut Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/2(2007-11-01), 509-515 1388-6150 90:2<509 2007 90 10973 https://doi.org/10.1007/s10973-006-7608-0 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-7608-0 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Mishra A. Department of Chemistry, University of Delhi, 110007, Delhi, India aut NATIONALLICENCE 700 1- Mishra S. Department of Chemistry, University of the Free State, 9866, Free State, South Africa aut NATIONALLICENCE 700 1- Manav N. Department of Chemistry, University of Delhi, 110007, Delhi, India aut NATIONALLICENCE 700 1- Kaushik N. Department of Chemistry, University of Delhi, 110007, Delhi, India aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/2(2007-11-01), 509-515 1388-6150 90:2<509 2007 90 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer