caa a22 4500 46319022X CHVBK 20180406164906.0 cr unu---uuuuu 170326e20071101xx s 000 0 eng 10.1007/s10973-006-7683-2 doi (NATIONALLICENCE)springer-10.1007/s10973-006-7683-2 The stability of inclusion compounds under heating [Elektronische Daten] Part I. Inclusion compounds of microporous manganese formate with included dioxane {Mn(HCOO)2·1/3C4H8O2} and tetrahydrofurane {Mn(HCOO)2·1/3C4H8O} [V. Logvinenko, D. Dybtsev, V. Fedin, V. Drebushchak, M. Yutkin] The thermal decomposition of two inclusion compounds Mn(HCOO)2·1/3C4H8O2 and Mn(HCOO)2·1/3C4H8O was studied in the inert atmosphere. The process of both dioxane, and tetrahydrofurane removal has two steps; the intermediate phase is unstable and kinetically hindered. Manganese formate is stable up to 330°C. Thermogravimetric data (obtained at different rates of linear heating) were processed with computer program (with ‘Model free' approach). Kinetic parameters were calculated for the first decomposition step, and the process is described by equation of n-order reaction with autocatalysis. Springer Science+Business Media, LLC., 2007 coordination compounds nationallicence inclusion compounds nationallicence ‘model free' kinetics nationallicence Logvinenko V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Ac. Lavrentyev Ave. 3, 630090, Novosibirsk-90, Russia aut Dybtsev D. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Ac. Lavrentyev Ave. 3, 630090, Novosibirsk-90, Russia aut Fedin V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Ac. Lavrentyev Ave. 3, 630090, Novosibirsk-90, Russia aut Drebushchak V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Ac. Lavrentyev Ave. 3, 630090, Novosibirsk-90, Russia aut Yutkin M. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Ac. Lavrentyev Ave. 3, 630090, Novosibirsk-90, Russia aut Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/2(2007-11-01), 463-467 1388-6150 90:2<463 2007 90 10973 https://doi.org/10.1007/s10973-006-7683-2 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-7683-2 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Logvinenko V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Ac. Lavrentyev Ave. 3, 630090, Novosibirsk-90, Russia aut NATIONALLICENCE 700 1- Dybtsev D. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Ac. Lavrentyev Ave. 3, 630090, Novosibirsk-90, Russia aut NATIONALLICENCE 700 1- Fedin V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Ac. Lavrentyev Ave. 3, 630090, Novosibirsk-90, Russia aut NATIONALLICENCE 700 1- Drebushchak V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Ac. Lavrentyev Ave. 3, 630090, Novosibirsk-90, Russia aut NATIONALLICENCE 700 1- Yutkin M. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Ac. Lavrentyev Ave. 3, 630090, Novosibirsk-90, Russia aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/2(2007-11-01), 463-467 1388-6150 90:2<463 2007 90 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer