caa a22 4500 463190289 CHVBK 20180406164906.0 cr unu---uuuuu 170326e20071101xx s 000 0 eng 10.1007/s10973-006-7949-8 doi (NATIONALLICENCE)springer-10.1007/s10973-006-7949-8 Effects of evaporation and melting on nonstoichiometry and inhomogeneity of LiInSe2 crystals [Elektronische Daten] [I. Vasilyeva, R. Nikolaev, V. Malakhov, L. Isaenko] Evaporation and compositional changes of the liquids above the melting point of LiInSe2 crystals have been characterized quantitatively by using special techniques of a rapid thermal analysis and differential dissolution. The occurrence of a liquid immiscible region in the Li2Se-rich side of the Li2Se-In2Se3 diagram and incongruent evaporation with the preferential evaporation of In2Se3 rising markedly above boiling point were determined from the peaks on the thermal curves and from precise control over the composition of the vapour and residual solid as a function of temperature. It was shown that both the processes could be the sources of nonstoichiometry and inhomogeneity of the LiInSe2 crystals. Springer Science+Business Media, LLC., 2007 evaporation nationallicence evolved gas analysis nationallicence LiInSe2 nationallicence melting nationallicence rapid thermal analysis nationallicence Vasilyeva I. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of RAS, 630090, Novosibirsk, Russia aut Nikolaev R. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of RAS, 630090, Novosibirsk, Russia aut Malakhov V. Boreskov Institute of Catalysis, Siberian Branch of RAS, 630090, Novosibirsk, Russia aut Isaenko L. Institute of Mineralogy and Petrography, Siberian Branch of RAS, 630090, Novosibirsk, Russia aut Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/2(2007-11-01), 601-605 1388-6150 90:2<601 2007 90 10973 https://doi.org/10.1007/s10973-006-7949-8 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-7949-8 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Vasilyeva I. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of RAS, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Nikolaev R. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of RAS, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Malakhov V. Boreskov Institute of Catalysis, Siberian Branch of RAS, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Isaenko L. Institute of Mineralogy and Petrography, Siberian Branch of RAS, 630090, Novosibirsk, Russia aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/2(2007-11-01), 601-605 1388-6150 90:2<601 2007 90 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer