caa a22 4500 463190335 CHVBK 20180406164907.0 cr unu---uuuuu 170326e20071101xx s 000 0 eng 10.1007/s10973-006-7729-5 doi (NATIONALLICENCE)springer-10.1007/s10973-006-7729-5 Investigation on the thermal decomposition some heterodinuclear NiII-MII complexes prepared from ONNO type reduced Schiff base compounds ( M II=ZnII, CdII) [Elektronische Daten] [M. Aksu, S. Durmuş, M. Sari, K. Emregül, I. Svoboda, H. Fuess, O. Atakol] N,N′-bis(salicylidene)-1,3-propanediamine (LH2), N,N′-bis(salicylidene)-2,2′-dimethyl-1,3-propanediamine (LDMH2), N,N′-bis(salicylidene)-2-hydroxy-1,3-propanediamine (LOH3), N,N′-bis(2-hydroxyacetophenylidene)-1,3-propanediamine (LACH2) and N,N′-bis(2-hydroxyacetophenone)-2,2′-dimethyl-1,3-propanediamine (LACDMH2) were synthesized and reduced to their phenol-amine form in alcoholic media using NaBH4 (LHH2, LDMHH2, LOHHH2, LACHH2 and LACDMHH2). Heterodinuclear complexes were synthesized using Ni(II), Zn(II) and Cd(II) salts, according to the template method in DMF media. The complex structures were analyzed using elemental analysis, IR spectroscopy, and thermogravimetry. Suitable crystals of only one complex were obtained and its structure determined using X-ray diffraction, NiLACH·CdBr2·DMF2, space group orthorhombic, Pbca, a=20.249, b=14.881, c=20.565 Å and Z=8. The heterodinuclear complexes were seen to be of [Ni·ligand·MX2·DMF2] structure (ligand=LH2−, LDMH2−, LOHH2−, LACH2−, LACDMH2−, M=ZnII, CdII, X=Br−, I−). Thermogravimetric analysis showed irreversible bond breakage of the coordinatively bonded DMF molecules followed by decomposition at this temperature. Springer Science+Business Media LLC, 2007 crystal structure nationallicence heterodinuclear complexes nationallicence ONNO type Schiff bases nationallicence thermal analysis nationallicence Aksu M. Yozgat Faculty of Science and Literature, Department of Chemistry, Erciyes University, Yozgat, Turkey aut Durmuş S. Faculty of Education, Abant Izzet Baysal University, Bolu, Turkey aut Sari M. Faculty of Education, Gazi University, Beşevler Ankara, Turkey aut Emregül K. Science Faculty, Department of Chemistry, Ankara University, Tando ğan, 06100, Ankara, Turkey aut Svoboda I. Strukturforschung, FB Materialwissenschaft, TU-Darmstadt Petersenstrasse 23, 64287, Darmstadt, Germany aut Fuess H. Strukturforschung, FB Materialwissenschaft, TU-Darmstadt Petersenstrasse 23, 64287, Darmstadt, Germany aut Atakol O. Science Faculty, Department of Chemistry, Ankara University, Tando ğan, 06100, Ankara, Turkey aut Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/2(2007-11-01), 541-547 1388-6150 90:2<541 2007 90 10973 https://doi.org/10.1007/s10973-006-7729-5 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-7729-5 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Aksu M. Yozgat Faculty of Science and Literature, Department of Chemistry, Erciyes University, Yozgat, Turkey aut NATIONALLICENCE 700 1- Durmuş S. Faculty of Education, Abant Izzet Baysal University, Bolu, Turkey aut NATIONALLICENCE 700 1- Sari M. Faculty of Education, Gazi University, Beşevler Ankara, Turkey aut NATIONALLICENCE 700 1- Emregül K. Science Faculty, Department of Chemistry, Ankara University, Tando ğan, 06100, Ankara, Turkey aut NATIONALLICENCE 700 1- Svoboda I. Strukturforschung, FB Materialwissenschaft, TU-Darmstadt Petersenstrasse 23, 64287, Darmstadt, Germany aut NATIONALLICENCE 700 1- Fuess H. Strukturforschung, FB Materialwissenschaft, TU-Darmstadt Petersenstrasse 23, 64287, Darmstadt, Germany aut NATIONALLICENCE 700 1- Atakol O. Science Faculty, Department of Chemistry, Ankara University, Tando ğan, 06100, Ankara, Turkey aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/2(2007-11-01), 541-547 1388-6150 90:2<541 2007 90 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer