caa a22 4500 463190378 CHVBK 20180406164907.0 cr unu---uuuuu 170326e20071101xx s 000 0 eng 10.1007/s10973-007-8386-z doi (NATIONALLICENCE)springer-10.1007/s10973-007-8386-z Assessment of the Fe-Sn-Zn phase diagram at 450°C [Elektronische Daten] Application to the batch galvanizing [Marie-Noelle Avettand-Fènoël, N. David, G. Reumont, J. Fiorani, M. Vilasi, P. Perrot] The Fe-Sn-Zn system is of interest because Sn is one element added to the Zn galvanizing bath to overcome the drawbacks due to the presence of Si in semi-killed steels. This work has been undertaken with the aim to understand the tin effect on the microstructure and the layers growth in batch galvanized coatings on low alloyed steels. Various experimental techniques such as metallography, scanning electron microscopy (SEM) coupled with X-ray energy dispersive spectroscopy (EDX) are used in order to characterize the microstructure and the properties of such coatings elaborated in a zinc bath enriched with tin. Solidification phenomena and layers growth mechanisms during galvanization are explained by means of the ternary phase diagram Fe-Sn-Zn at 450°C. The Calphad method allows to obtain this phase diagram from the three optimized binary phase diagrams Fe-Sn, Fe-Zn and Sn-Zn and some experimental data inside the ternary Fe-Sn-Zn system. Springer Science+Business Media, LLC., 2007 batch galvanizing nationallicence Calphad method nationallicence Fe-Sn-Zn diagram nationallicence Avettand-Fènoël Marie-Noelle Laboratoire de Métallurgie Physique et Génie des Matériaux, U.M.R. C.N.R.S. 8517, Université de Lille 1, 59650, Villeneuve D'Ascq, France aut David N. Laboratoire de Chimie du Solide Minéral, U.M.R. C.N.R.S. 7555, Université Henri Poincaré, Nancy I, 54506, Vandoeuvre Les Nancy, France aut Reumont G. Laboratoire de Métallurgie Physique et Génie des Matériaux, U.M.R. C.N.R.S. 8517, Université de Lille 1, 59650, Villeneuve D'Ascq, France aut Fiorani J. Laboratoire de Chimie du Solide Minéral, U.M.R. C.N.R.S. 7555, Université Henri Poincaré, Nancy I, 54506, Vandoeuvre Les Nancy, France aut Vilasi M. Laboratoire de Chimie du Solide Minéral, U.M.R. C.N.R.S. 7555, Université Henri Poincaré, Nancy I, 54506, Vandoeuvre Les Nancy, France aut Perrot P. Laboratoire de Métallurgie Physique et Génie des Matériaux, U.M.R. C.N.R.S. 8517, Université de Lille 1, 59650, Villeneuve D'Ascq, France aut Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/2(2007-11-01), 329-332 1388-6150 90:2<329 2007 90 10973 https://doi.org/10.1007/s10973-007-8386-z text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-007-8386-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Avettand-Fènoël Marie-Noelle Laboratoire de Métallurgie Physique et Génie des Matériaux, U.M.R. C.N.R.S. 8517, Université de Lille 1, 59650, Villeneuve D'Ascq, France aut NATIONALLICENCE 700 1- David N. Laboratoire de Chimie du Solide Minéral, U.M.R. C.N.R.S. 7555, Université Henri Poincaré, Nancy I, 54506, Vandoeuvre Les Nancy, France aut NATIONALLICENCE 700 1- Reumont G. Laboratoire de Métallurgie Physique et Génie des Matériaux, U.M.R. C.N.R.S. 8517, Université de Lille 1, 59650, Villeneuve D'Ascq, France aut NATIONALLICENCE 700 1- Fiorani J. Laboratoire de Chimie du Solide Minéral, U.M.R. C.N.R.S. 7555, Université Henri Poincaré, Nancy I, 54506, Vandoeuvre Les Nancy, France aut NATIONALLICENCE 700 1- Vilasi M. Laboratoire de Chimie du Solide Minéral, U.M.R. C.N.R.S. 7555, Université Henri Poincaré, Nancy I, 54506, Vandoeuvre Les Nancy, France aut NATIONALLICENCE 700 1- Perrot P. Laboratoire de Métallurgie Physique et Génie des Matériaux, U.M.R. C.N.R.S. 8517, Université de Lille 1, 59650, Villeneuve D'Ascq, France aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/2(2007-11-01), 329-332 1388-6150 90:2<329 2007 90 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer