caa a22 4500 463190432 CHVBK 20180406164907.0 cr unu---uuuuu 170326e20071101xx s 000 0 eng 10.1007/s10973-006-7980-9 doi (NATIONALLICENCE)springer-10.1007/s10973-006-7980-9 Synthesis and characterization of new metal(II) complexes with formates and some nitrogen donor ligands [Elektronische Daten] [D. Czakis-Sulikowska, A. Czylkowska, J. Radwańska-Doczekalska, R. Grodzki, E. Wojciechowska] New mixed-ligands complexes with empirical formulae: M(2,4′-bpy)2L2·H2O (M(II)Zn, Cd), Zn(2-bpy)3L2·4H2O, Cd(2-bpy)2L2·3H2O, M(phen)L2·2H2O (where M(II)=Mn, Ni, Zn, Cd; 2,4′-bpy=2,4′-bipyridine, 2-bpy=2,2′-bipyridine, phen=1,10-phenanthroline, L=HCOO−) were prepared in pure solid state. They were characterized by chemical, thermal and X-ray powder diffraction analysis, IR spectroscopy, molar conductance in MeOH, DMF and DMSO. Examinations of OCO− absorption bands suggest versatile coordination behaviour of obtained complexes. The 2,4′-bpy acts as monodentate ligand; 2-bpy and phen as chelating ligands. Thermal studies were performed in static air atmosphere. When the temperature raised the dehydration processes started. The final decomposition products, namely MO (Ni, Zn, Cd) and Mn3O4, were identified by X-ray diffraction. Springer Science+Business Media, LLC., 2007 bipyridine isomers nationallicence IR spectra nationallicence mixed-ligands complexes nationallicence thermal decomposition nationallicence 1,10-phenanthroline nationallicence X-ray diffraction nationallicence Czakis-Sulikowska D. Institute of General and Ecological Chemistry, Technical University of Łódź, Łódź, Poland aut Czylkowska A. Institute of General and Ecological Chemistry, Technical University of Łódź, Łódź, Poland aut Radwańska-Doczekalska J. Institute of General and Ecological Chemistry, Technical University of Łódź, Łódź, Poland aut Grodzki R. Institute of General and Ecological Chemistry, Technical University of Łódź, Łódź, Poland aut Wojciechowska E. Institute of General and Ecological Chemistry, Technical University of Łódź, Łódź, Poland aut Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/2(2007-11-01), 557-564 1388-6150 90:2<557 2007 90 10973 https://doi.org/10.1007/s10973-006-7980-9 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-7980-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Czakis-Sulikowska D. Institute of General and Ecological Chemistry, Technical University of Łódź, Łódź, Poland aut NATIONALLICENCE 700 1- Czylkowska A. Institute of General and Ecological Chemistry, Technical University of Łódź, Łódź, Poland aut NATIONALLICENCE 700 1- Radwańska-Doczekalska J. Institute of General and Ecological Chemistry, Technical University of Łódź, Łódź, Poland aut NATIONALLICENCE 700 1- Grodzki R. Institute of General and Ecological Chemistry, Technical University of Łódź, Łódź, Poland aut NATIONALLICENCE 700 1- Wojciechowska E. Institute of General and Ecological Chemistry, Technical University of Łódź, Łódź, Poland aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/2(2007-11-01), 557-564 1388-6150 90:2<557 2007 90 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer