caa a22 4500 463190629 CHVBK 20180406164907.0 cr unu---uuuuu 170326e20071101xx s 000 0 eng 10.1007/s10973-006-7689-9 doi (NATIONALLICENCE)springer-10.1007/s10973-006-7689-9 Three new dinuclear silver(I) complexes derived from pyrazolyl type ligands [Elektronische Daten] Crystal structure and thermal decomposition [O. Atakol, H. Fuess, R. Kurtaran, A. Akay, C. Arici, Ü. Ergun, K. Emregül] Three NNN type ligands derived from 2,6-dichlorpyroidine, pyrazol and 3,5-dimethylpyrazole and their silver complexes were prepared in methanol media. The complex structures were characterized using IR spectroscopy, X-ray diffraction and elemental analysis. X-ray studies showed the complexes to be dimeric in structure. The two nitrogen atoms of the ligand coordinated the first Ag(I) ion whereas the second Ag(I) ion was coordinated by the third nitrogen donor. The nitrate structure was not ionic in a done of its oxygen atoms coordinated an Ag(I) ion. The Ag(I) ion was seen to be situated in a deformed tetrahedral coordination sphere. Thermogravimetric studies showed the complexes to decompose similar to explosive material. The decomposition temperature was observed to increase with increasing hydrogen atoms in the structure. Springer Science+Business Media, LLC., 2007 DTA nationallicence pyrazolyl nationallicence silver(I) complex nationallicence TG nationallicence Atakol O. Science Faculty, Department of Chemistry, Ankara University, Tando ğan, 06100, Ankara, Turkey aut Fuess H. Strukturforschung, FB Materialwissenschaft, Technische Hochschule, Darmstadt Petersenstrasse 23, 64287, Darmstadt, Germany aut Kurtaran R. Department of Chemistry, Faculty of Arts and Science, University of Balıkesir, Balıkesir, Turkey aut Akay A. Science Faculty, Department of Chemistry, Ankara University, Tando ğan, 06100, Ankara, Turkey aut Arici C. Department of Physical Engineering, Hacettepe University, 06532, Beytepe Ankara, Turkey aut Ergun Ü. Science Faculty, Department of Chemistry, Ankara University, Tando ğan, 06100, Ankara, Turkey aut Emregül K. Science Faculty, Department of Chemistry, Ankara University, Tando ğan, 06100, Ankara, Turkey aut Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/2(2007-11-01), 517-523 1388-6150 90:2<517 2007 90 10973 https://doi.org/10.1007/s10973-006-7689-9 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-7689-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Atakol O. Science Faculty, Department of Chemistry, Ankara University, Tando ğan, 06100, Ankara, Turkey aut NATIONALLICENCE 700 1- Fuess H. Strukturforschung, FB Materialwissenschaft, Technische Hochschule, Darmstadt Petersenstrasse 23, 64287, Darmstadt, Germany aut NATIONALLICENCE 700 1- Kurtaran R. Department of Chemistry, Faculty of Arts and Science, University of Balıkesir, Balıkesir, Turkey aut NATIONALLICENCE 700 1- Akay A. Science Faculty, Department of Chemistry, Ankara University, Tando ğan, 06100, Ankara, Turkey aut NATIONALLICENCE 700 1- Arici C. Department of Physical Engineering, Hacettepe University, 06532, Beytepe Ankara, Turkey aut NATIONALLICENCE 700 1- Ergun Ü. Science Faculty, Department of Chemistry, Ankara University, Tando ğan, 06100, Ankara, Turkey aut NATIONALLICENCE 700 1- Emregül K. Science Faculty, Department of Chemistry, Ankara University, Tando ğan, 06100, Ankara, Turkey aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer US; http://www.springer-ny.com 90/2(2007-11-01), 517-523 1388-6150 90:2<517 2007 90 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer