caa a22 4500 463190688 CHVBK 20180406164908.0 cr unu---uuuuu 170326e20070701xx s 000 0 eng 10.1007/s10973-006-7534-1 doi (NATIONALLICENCE)springer-10.1007/s10973-006-7534-1 Effect of LiPF6 on the thermal behaviors of four organic solvents for lithium ion batteries [Elektronische Daten] [Q. Wang, J. Sun, G. Chu, X. Yao, C. Chen] The thermal behaviors of four organic solvents with/without LiPF6 were measured by C80 microcalorimeter at a 0.2°C min−1 heating rate. With the addition of 1 M LiPF6, the ethylene carbonate (EC) and propylene carbonate (PC) show the exothermic peaks at elevated temperature, which lessen their stabilities. The exothermic peak temperatures of EC and PC based LiPF6 solutions are at 212 and 223°C, respectively, in argon filled vessel. However, two endothermic peak temperatures were detected in diethyl carbonate (DEC) based LiPF6 solution at 182 and 252.5°C, respectively, in argon filled vessel. Dimethyl carbonate (DMC) based LiPF6 solution shows two endothermic peak temperatures at 68.5 and 187°C in argon filled vessel at elevated temperature. Consequently, it is concluded that LiPF6 play a key role in the thermal behavior of its organic solution. Springer Science+Business Media LLC, 2007 C80 microcalorimeter nationallicence lithium ion battery nationallicence organic solvents nationallicence thermal behavior nationallicence Wang Q. State Key Laboratory of Fire Science, University of Science and Technology of China, 230026, Hefei, P.R. China aut Sun J. State Key Laboratory of Fire Science, University of Science and Technology of China, 230026, Hefei, P.R. China aut Chu G. State Key Laboratory of Fire Science, University of Science and Technology of China, 230026, Hefei, P.R. China aut Yao X. Department of Materials Science and Engineering, University of Science and Technology of China, 230026, Hefei, P.R. China aut Chen C. Department of Materials Science and Engineering, University of Science and Technology of China, 230026, Hefei, P.R. China aut Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 89/1(2007-07-01), 245-250 1388-6150 89:1<245 2007 89 10973 https://doi.org/10.1007/s10973-006-7534-1 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-7534-1 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wang Q. State Key Laboratory of Fire Science, University of Science and Technology of China, 230026, Hefei, P.R. China aut NATIONALLICENCE 700 1- Sun J. State Key Laboratory of Fire Science, University of Science and Technology of China, 230026, Hefei, P.R. China aut NATIONALLICENCE 700 1- Chu G. State Key Laboratory of Fire Science, University of Science and Technology of China, 230026, Hefei, P.R. China aut NATIONALLICENCE 700 1- Yao X. Department of Materials Science and Engineering, University of Science and Technology of China, 230026, Hefei, P.R. China aut NATIONALLICENCE 700 1- Chen C. Department of Materials Science and Engineering, University of Science and Technology of China, 230026, Hefei, P.R. China aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 89/1(2007-07-01), 245-250 1388-6150 89:1<245 2007 89 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer