caa a22 4500 46319098X CHVBK 20180406164909.0 cr unu---uuuuu 170326e20070701xx s 000 0 eng 10.1007/s10973-005-7473-2 doi (NATIONALLICENCE)springer-10.1007/s10973-005-7473-2 A comparative study on the thermal decomposition of some transition metal maleates and fumarates [Elektronische Daten] [B. Randhawa, M. Kaur] Thermal decomposition of M(mal/fum)·xH2O (M=Mn, Co, Ni) has been studied in static air atmosphere from ambient to 500°C employing TG-DTG-DTA, XRD and IR spectroscopic techniques. After dehydration the anhydrous maleate salts decompose to metal oxalate in the temperature range of 320-360°C, which at higher temperature undergo an abrupt oxidative pyrolysis to oxides. The anhydrous fumarate salts have been found to decompose directly to oxide phase. A comparison of thermal analysis reveals that fumarates are thermally more stable than maleates. Springer Science+Business Media LLC, 2007 metal fumarates nationallicence metal maleates nationallicence TG-DTG-DTA nationallicence thermal decomposition nationallicence XRD nationallicence Randhawa B. Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India aut Kaur M. Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India aut Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 89/1(2007-07-01), 251-255 1388-6150 89:1<251 2007 89 10973 https://doi.org/10.1007/s10973-005-7473-2 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-005-7473-2 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Randhawa B. Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India aut NATIONALLICENCE 700 1- Kaur M. Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 89/1(2007-07-01), 251-255 1388-6150 89:1<251 2007 89 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer