caa a22 4500 463191722 CHVBK 20180406164911.0 cr unu---uuuuu 170326e20070801xx s 000 0 eng 10.1007/s10973-006-8219-5 doi (NATIONALLICENCE)springer-10.1007/s10973-006-8219-5 Wunderlich B. Department of Chemistry, University of Tennessee, 37996-1600, Knoxville, TN, USA aut Thermal analysis of macromolecules [Elektronische Daten] A personal review [B. Wunderlich] This review traces the development of thermal analysis over the last 50 years as it was experienced and contributed to by the author. The article touches upon the beginning of calorimetry and thermal analysis of polymers, the development of differential scanning calorimetry (DSC), single-run DSC, and other special instrumentations, up to the recent addition of modulation to calorimetry and superfast calorimetry. Many new words and phrases have been introduced to the field by the author and his students, leaving a trail of the varied interests over 50 years. It began with cold crystallization and more recently the terms oriented, intermediate phase, glass transitions of crystals, and decoupled chain segments were coined. In-between the following phenomena were named and studied: extended-chain crystals, irreversible thermodynamics of melting of polymer crystals, zero-entropy-production melting, dynamic differential thermal analysis (DDTA), the rule of constant increase of C p per mobile bead within a molecule at the glass transition temperature, superheating of polymer crystals, melting kinetics, crystallization during polymerization, chin-folding principle, molecular nucleation, rigid amorphous phase, system of classifying molecules, macroconformations, amorphous defects, rules for the entropy of fusion based on molecular shape and flexibility, single-molecule single-crystals, systems for classifying phases and mesophases including condis phases, and the globally metastable semicrystalline polymers with reversible, local subsystems. Springer Science+Business Media LLC, 2007 DSC nationallicence fifty-year review nationallicence macromolecules nationallicence molecular motion nationallicence nonequilibrium nationallicence phases nationallicence thermal analysis nationallicence thermodynamics nationallicence TMDSC nationallicence Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 89/2(2007-08-01), 321-356 1388-6150 89:2<321 2007 89 10973 https://doi.org/10.1007/s10973-006-8219-5 text/html Onlinezugriff via DOI 1 review-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-8219-5 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Wunderlich B. Department of Chemistry, University of Tennessee, 37996-1600, Knoxville, TN, USA aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 89/2(2007-08-01), 321-356 1388-6150 89:2<321 2007 89 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence SWISSBIB 463191722 BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer