caa a22 4500 463191773 CHVBK 20180406164911.0 cr unu---uuuuu 170326e20070801xx s 000 0 eng 10.1007/s10973-006-8161-6 doi (NATIONALLICENCE)springer-10.1007/s10973-006-8161-6 A historical and current perspective on predicting thermal cookoff behavior [Elektronische Daten] [A. Burnham, R. Weese, A. Wemhoff, J. Maienschein] Prediction of thermal explosions using chemical kinetic models dates back nearly a century. However, it has only been within the past 25 years that kinetic models and digital computers made reliable predictions possible. Two basic approaches have been used to derive chemical kinetic models for high explosives: [1] measurement of the reaction rate of small samples by mass loss (thermogravimetric analysis, TG), heat release (differential scanning calorimetry, DSC), or evolved gas analysis (mass spectrometry, infrared spectrometry, etc.) or [2] inference from larger-scale experiments measuring the critical temperature (T m, lowest T for self-initiation), the time to explosion as a function of temperature, and sometimes a few other results, such as temperature profiles. Some of the basic principles of chemical kinetics involved are outlined, and major advances in these two approaches through the years are reviewed. Springer Science+Business Media LLC, 2007 chemical kinetics nationallicence energetic materials nationallicence explosives nationallicence thermal explosions nationallicence thermal ignition nationallicence Burnham A. Energetic Materials Center, Lawrence Livermore National Laboratory, 94550, Livermore, CA, USA aut Weese R. Energetic Materials Center, Lawrence Livermore National Laboratory, 94550, Livermore, CA, USA aut Wemhoff A. Energetic Materials Center, Lawrence Livermore National Laboratory, 94550, Livermore, CA, USA aut Maienschein J. Energetic Materials Center, Lawrence Livermore National Laboratory, 94550, Livermore, CA, USA aut Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 89/2(2007-08-01), 407-415 1388-6150 89:2<407 2007 89 10973 https://doi.org/10.1007/s10973-006-8161-6 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-8161-6 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Burnham A. Energetic Materials Center, Lawrence Livermore National Laboratory, 94550, Livermore, CA, USA aut NATIONALLICENCE 700 1- Weese R. Energetic Materials Center, Lawrence Livermore National Laboratory, 94550, Livermore, CA, USA aut NATIONALLICENCE 700 1- Wemhoff A. Energetic Materials Center, Lawrence Livermore National Laboratory, 94550, Livermore, CA, USA aut NATIONALLICENCE 700 1- Maienschein J. Energetic Materials Center, Lawrence Livermore National Laboratory, 94550, Livermore, CA, USA aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 89/2(2007-08-01), 407-415 1388-6150 89:2<407 2007 89 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer