caa a22 4500 463192036 CHVBK 20180406164912.0 cr unu---uuuuu 170326e20070801xx s 000 0 eng 10.1007/s10973-006-7602-6 doi (NATIONALLICENCE)springer-10.1007/s10973-006-7602-6 Two Mn(II) chloride complexes containing guest molecules [Elektronische Daten] Solvothermal syntheses, crystal structures and thermal decomposition [Q. Yang, S. Chen, S. Gao] Two phenanthroline-manganese inclusion complexes with [MnCl(H2O)(phen)2]+ core have been synthesized and characterized by single crystal X-ray diffraction, elemental analyses, IR spectra, thermogravimetric analyses. Uncoordinated 2-mercaptothiazole (tzdtH) and 2-mercaptobenzothiazole (bztzH) as guest molecules are included in the complexes with formulas [MnCl(H2O)(phen)2]Cl·tzdtH (1) and {[MnCl(H2O)(phen)2]Cl}2·bztzH (2). X-ray structural analyses for complexes revealed that the complex 1 is triclinic, space group P1 with a=9.724(1) Å, b=11.858(1) Å, c=12.644(2) Å; β=89.056(2)°; Z=2, D c=1.513 Mg m−3, F(000)=638 and the complex 2 is triclinic, space group P1 with a=9.861(1) Å, b=11.476(1) Å; c=12.908(3) Å; β=84.991(2)°; Z=1, D c=1.511 Mg m−3, F(000)=600. Two complexes exhibit high stability up to 650°C. The molar specific heat capacities for the two complexes 1 and 2 can be estimated as being 96.175±0.332 and 72.505±0.364 J mol−1 K−1 at 298.15 K by RD496-III microcalorimeter, respectively. Springer Science+Business Media LLC, 2007 crystal structure nationallicence manganese nationallicence 2-mercaptobenzothiazole nationallicence 2-mercaptothiazole nationallicence phenanthroline nationallicence thermal analysis nationallicence Yang Q. Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, 710069, Xi'an, P. R. China aut Chen S. Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, 710069, Xi'an, P. R. China aut Gao S. Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, 710069, Xi'an, P. R. China aut Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 89/2(2007-08-01), 567-571 1388-6150 89:2<567 2007 89 10973 https://doi.org/10.1007/s10973-006-7602-6 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-7602-6 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Yang Q. Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, 710069, Xi'an, P. R. China aut NATIONALLICENCE 700 1- Chen S. Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, 710069, Xi'an, P. R. China aut NATIONALLICENCE 700 1- Gao S. Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, 710069, Xi'an, P. R. China aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 89/2(2007-08-01), 567-571 1388-6150 89:2<567 2007 89 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer