caa a22 4500 463192125 CHVBK 20180406164912.0 cr unu---uuuuu 170326e20070101xx s 000 0 eng 10.1007/s10973-006-7807-8 doi (NATIONALLICENCE)springer-10.1007/s10973-006-7807-8 Danil de Namor Angela Thermochemistry Laboratory, Chemistry Division, School of Biomedical and Molecular Sciences, University of Surrey, GU2 7XH, Guildford, Surrey, UK aut Thefluoride dilemma [Elektronische Daten] Thermodynamicsof anion recognition by calixpyrroles [Angela Danil de Namor] The implications of environmental contamination by fluoride on human health call upon the need for the development of monitoring systems for the ‘in situ' detection of fluoride in contaminated sources and new technologies approaches for their removal. This paper reports recent work on the design of calixpyrrole receptors selective for the fluoride anion. The various steps undertaken for the thermodynamic characterization of these receptors and their anionic complexes are discussed. Thus based on thermodynamic data, the medium and ligand effects on selectivity are quantitatively assessed using representative calixpyrrole derivatives. Springer-Verlag, 2006 calixpyrrole receptors nationallicence detection of fluorides nationallicence environmental contamination nationallicence Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 87/1(2007-01-01), 7-14 1388-6150 87:1<7 2007 87 10973 https://doi.org/10.1007/s10973-006-7807-8 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-7807-8 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Danil de Namor Angela Thermochemistry Laboratory, Chemistry Division, School of Biomedical and Molecular Sciences, University of Surrey, GU2 7XH, Guildford, Surrey, UK aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 87/1(2007-01-01), 7-14 1388-6150 87:1<7 2007 87 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer