caa a22 4500 463192214 CHVBK 20180406164912.0 cr unu---uuuuu 170326e20070101xx s 000 0 eng 10.1007/s10973-006-7826-5 doi (NATIONALLICENCE)springer-10.1007/s10973-006-7826-5 Vecchio S. Dipartimento di Ingegneria Chimica, dei Materiali, delle Materie prime e Metallurgia, Università di Roma ‘La Sapienza', Via del Castro Laurenziano 7, 00161, Roma, Italy aut Contributionof thermal analysis to the description of transport phenomena of pesticides [Elektronische Daten] Vaporization enthalpies of two acetanilidepesticides [S. Vecchio] The vaporization enthalpies of two acetanilide pesticides, alachlor (2',6'-diethyl-N-(methoxymethyl)-2-chloroacetanilide) and metolachlor (2-chloro-N-(2-ethyl-6-methylphenyl)-N-[(1S)-2-methoxy-1-methylethyl] acetamide), were determined by processing non-isothermal thermogravimetry data according to the Clausius-Clapeyron equation. The reliability of the procedure proposed was tested carrying out some experiments at different heating rates using acetanilide as a reference compound. A good agreement is found among the vaporization enthalpies derived from all the multi-heating rate experiments as well as with the one predicted from the vapor pressure data taken from literature. The vaporization temperatures (T vap=470±2 K and T vap=479±2 K) and enthalpies (Δvap H°(436 K)=85±1 kJ mol-1 and Δvap H°(436 K)=70±1 kJ mol-1) for alachlor and metolachlor, were selected, respectively. Springer-Verlag, 2007 acetanilide pesticides nationallicence alachlor nationallicence Clausius-Clapeyron equation nationallicence metolachlor nationallicence thermogravimetry nationallicence vaporization enthalpy nationallicence Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 87/1(2007-01-01), 79-83 1388-6150 87:1<79 2007 87 10973 https://doi.org/10.1007/s10973-006-7826-5 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-7826-5 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Vecchio S. Dipartimento di Ingegneria Chimica, dei Materiali, delle Materie prime e Metallurgia, Università di Roma ‘La Sapienza', Via del Castro Laurenziano 7, 00161, Roma, Italy aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 87/1(2007-01-01), 79-83 1388-6150 87:1<79 2007 87 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer