caa a22 4500 463192265 CHVBK 20180406164912.0 cr unu---uuuuu 170326e20070101xx s 000 0 eng 10.1007/s10973-006-7812-y doi (NATIONALLICENCE)springer-10.1007/s10973-006-7812-y Studyof the temperature-programmed oxidative degradation of hydrocarbons over Ce-basedcatalysts by evolved gas analysis [Elektronische Daten] [J. Gutiérrez-Ortiz, Beatriz de Rivas, R. López-Fonseca, J. González-Velasco] The catalytic behaviour of ceria, zirconia and ceria-zirconia mixed oxides in the temperature-programmed degradation of toluene and n-hexane was analysed by means of evolved gas analysis (mass spectrometry). Pure cerium oxide resulted the most active catalyst in the oxidation of both compounds. This fact revealed the crucial role of the surface oxygen species in the decomposition of this type of hydrocarbons. The low affinity of CeO2 for H2O and CO2, the major oxidation products, may be also responsible for the observed highly active catalytic behaviour. Springer-Verlag, 2006 ceria-zirconia mixed oxides nationallicence evolved gas analysis nationallicence n -hexane nationallicence temperature-programmed oxidative degradation nationallicence toluene nationallicence Gutiérrez-Ortiz J. Chemical Technologies for Environmental Sustainability Group, Department of Chemical Engineering, Faculty of Science and Technology, Universidad del País Vasco/EHU, P.O. Box 644, 48080, Bilbao, Spain aut de Rivas Beatriz Chemical Technologies for Environmental Sustainability Group, Department of Chemical Engineering, Faculty of Science and Technology, Universidad del País Vasco/EHU, P.O. Box 644, 48080, Bilbao, Spain aut López-Fonseca R. Chemical Technologies for Environmental Sustainability Group, Department of Chemical Engineering, Faculty of Science and Technology, Universidad del País Vasco/EHU, P.O. Box 644, 48080, Bilbao, Spain aut González-Velasco J. Chemical Technologies for Environmental Sustainability Group, Department of Chemical Engineering, Faculty of Science and Technology, Universidad del País Vasco/EHU, P.O. Box 644, 48080, Bilbao, Spain aut Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 87/1(2007-01-01), 55-60 1388-6150 87:1<55 2007 87 10973 https://doi.org/10.1007/s10973-006-7812-y text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-7812-y text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Gutiérrez-Ortiz J. Chemical Technologies for Environmental Sustainability Group, Department of Chemical Engineering, Faculty of Science and Technology, Universidad del País Vasco/EHU, P.O. Box 644, 48080, Bilbao, Spain aut NATIONALLICENCE 700 1- de Rivas Beatriz Chemical Technologies for Environmental Sustainability Group, Department of Chemical Engineering, Faculty of Science and Technology, Universidad del País Vasco/EHU, P.O. Box 644, 48080, Bilbao, Spain aut NATIONALLICENCE 700 1- López-Fonseca R. Chemical Technologies for Environmental Sustainability Group, Department of Chemical Engineering, Faculty of Science and Technology, Universidad del País Vasco/EHU, P.O. Box 644, 48080, Bilbao, Spain aut NATIONALLICENCE 700 1- González-Velasco J. Chemical Technologies for Environmental Sustainability Group, Department of Chemical Engineering, Faculty of Science and Technology, Universidad del País Vasco/EHU, P.O. Box 644, 48080, Bilbao, Spain aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 87/1(2007-01-01), 55-60 1388-6150 87:1<55 2007 87 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer