caa a22 4500 463192362 CHVBK 20180406164912.0 cr unu---uuuuu 170326e20070101xx s 000 0 eng 10.1007/s10973-006-7819-4 doi (NATIONALLICENCE)springer-10.1007/s10973-006-7819-4 Rubidiumand lithium butanoates binary phase diagram [Elektronische Daten] Formation of a stable lyotropic liquid crystal phase and twomixed salts [F. Martínez Casado, M. Ramos Riesco, J. Cheda] The temperature and enthalpy vs. composition diagrams of the binary system [xC3H7CO2Li+(1-x)C3H7CO2Rb], where x=mole fraction, were determined by differential scanning calorimetry (DSC). This binary systems displays the formation of two mixed salts with a composition 1:1 and 1:2, which melt incongruently at T fus=590.5 K, with Δfus H m=11.6 kJ mol-1, and congruently at T fus=614.5 K, with Δfus H m=20.2 kJ mol-1, respectively. The phase diagram also presents an ionic liquid-crystalline phase in a wide temperature range: 95 K. Springer-Verlag, 2006 binary phase diagram nationallicence eutectic and peritectic points nationallicence lithium butanoate nationallicence lyotropic liquid crystal nationallicence mixed salts nationallicence rubidium butanoate nationallicence Martínez Casado F. Departamento Química Física I, Facultad de Ciencias Químicas, Universidad Complutense, 28040, Madrid, Spain aut Ramos Riesco M. Departamento Química Física I, Facultad de Ciencias Químicas, Universidad Complutense, 28040, Madrid, Spain aut Cheda J. Departamento Química Física I, Facultad de Ciencias Químicas, Universidad Complutense, 28040, Madrid, Spain aut Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 87/1(2007-01-01), 73-77 1388-6150 87:1<73 2007 87 10973 https://doi.org/10.1007/s10973-006-7819-4 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-7819-4 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Martínez Casado F. Departamento Química Física I, Facultad de Ciencias Químicas, Universidad Complutense, 28040, Madrid, Spain aut NATIONALLICENCE 700 1- Ramos Riesco M. Departamento Química Física I, Facultad de Ciencias Químicas, Universidad Complutense, 28040, Madrid, Spain aut NATIONALLICENCE 700 1- Cheda J. Departamento Química Física I, Facultad de Ciencias Químicas, Universidad Complutense, 28040, Madrid, Spain aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 87/1(2007-01-01), 73-77 1388-6150 87:1<73 2007 87 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer