caa a22 4500 463192494 CHVBK 20180406164913.0 cr unu---uuuuu 170326e20070101xx s 000 0 eng 10.1007/s10973-006-7800-2 doi (NATIONALLICENCE)springer-10.1007/s10973-006-7800-2 Mechanicalproperties and morphology of epoxy/poly(vinyl acetate)/poly(4-vinyl phenol)brominated system [Elektronische Daten] [Margarita Prolongo, C. Arribas, Catalina Salom, Rosa Masegosa] Diglycidyl ether of bisfenol-A (DGEBA)/poly(vinyl acetate) (PVAc)/poly(4-vinyl phenol) brominated (PVPhBr) ternary blends cured with 4,4'-diaminodiphenylmethane (DDM) were investigated by differential scanning calorimetry (DSC), dynamic mechanical thermal analysis (DMTA) and scanning electron microscopy (SEM). Homogeneous (DGEBA+DDM)/PVPhBr networks with a unique T g are generated. Ternary blends (DGEBA+DDM)/PVAc/PVPhBr are initially miscible and phase separate upon curing arising two T gs that correspond to a PVAc-rich phase and to epoxy network phase. Increasing the PVPhBr content the T gof the PVAc phase move to higher temperatures as a consequence of the PVAc-PVPhBr interactions. Different morphologies are generated as a function of the blend composition. Springer-Verlag, 2006 epoxy nationallicence glass transition nationallicence morphology nationallicence poly(vinyl acetate) nationallicence poly(4-vinyl phenol) brominated nationallicence ternary blends nationallicence Prolongo Margarita Departamento de Materiales y Producción Aeroespacial, E.T.S.I. Aeronáuticos Universidad Politécnica de Madrid, Madrid, Spain aut Arribas C. Departamento de Materiales y Producción Aeroespacial, E.T.S.I. Aeronáuticos Universidad Politécnica de Madrid, Madrid, Spain aut Salom Catalina Departamento de Materiales y Producción Aeroespacial, E.T.S.I. Aeronáuticos Universidad Politécnica de Madrid, Madrid, Spain aut Masegosa Rosa Departamento de Física y Química Aplicadas a la Técnica Aeronáutica, E.U.I.T. Aeronáutica Universidad Politécnica de Madrid, Madrid, Spain aut Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 87/1(2007-01-01), 33-39 1388-6150 87:1<33 2007 87 10973 https://doi.org/10.1007/s10973-006-7800-2 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-7800-2 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Prolongo Margarita Departamento de Materiales y Producción Aeroespacial, E.T.S.I. Aeronáuticos Universidad Politécnica de Madrid, Madrid, Spain aut NATIONALLICENCE 700 1- Arribas C. Departamento de Materiales y Producción Aeroespacial, E.T.S.I. Aeronáuticos Universidad Politécnica de Madrid, Madrid, Spain aut NATIONALLICENCE 700 1- Salom Catalina Departamento de Materiales y Producción Aeroespacial, E.T.S.I. Aeronáuticos Universidad Politécnica de Madrid, Madrid, Spain aut NATIONALLICENCE 700 1- Masegosa Rosa Departamento de Física y Química Aplicadas a la Técnica Aeronáutica, E.U.I.T. Aeronáutica Universidad Politécnica de Madrid, Madrid, Spain aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 87/1(2007-01-01), 33-39 1388-6150 87:1<33 2007 87 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer