caa a22 4500 463192850 CHVBK 20180406164914.0 cr unu---uuuuu 170326e20070301xx s 000 0 eng 10.1007/s10973-006-7858-x doi (NATIONALLICENCE)springer-10.1007/s10973-006-7858-x Aninvestigation of the thermal behavior of heterobimetallic species containingcopper(II) and tetracyanopalladate(II) [Elektronische Daten] [A. Legendre, J. Correa, G. Bannach, A. Mauro, M. Ionashiro] Synthesis, characterization and thermal behavior of four compounds that have the general formula [Cu{Pd(CN)4}(L)x]n, in which en=1,2-diaminoethane and pn=1,3-diaminopropane (L=en, x=1 (I); L=pn, x=1 (II); L=en, x=2 (III); L=pn, x=2 (IV)) were described in this work. The complexes were studied by elemental analysis, infrared spectroscopy (IR), differential thermal analysis (DTA) and thermogravimetry (TG) and the residues of the thermal decomposition were characterized by X-ray powder diffraction and found as a mixture of CuO and PdO. The stoichiometry of the compounds was established via thermogravimetric and elemental analyses and their structures were proposed as coordination polymers based on their infrared spectra. The following thermal stability sequence was found: IV<I=II<III. Springer-Verlag, 2007 amines nationallicence copper(II) complexes nationallicence tetracyanopalladate(II) nationallicence thermal behavior nationallicence Legendre A. Instituto de Química de Araraquara, UNESP, C.P. 355, 14800-900, Araraquara, SP, Brazil aut Correa J. Instituto de Química de Araraquara, UNESP, C.P. 355, 14800-900, Araraquara, SP, Brazil aut Bannach G. Instituto de Química de Araraquara, UNESP, C.P. 355, 14800-900, Araraquara, SP, Brazil aut Mauro A. Instituto de Química de Araraquara, UNESP, C.P. 355, 14800-900, Araraquara, SP, Brazil aut Ionashiro M. Instituto de Química de Araraquara, UNESP, C.P. 355, 14800-900, Araraquara, SP, Brazil aut Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 87/3(2007-03-01), 779-782 1388-6150 87:3<779 2007 87 10973 https://doi.org/10.1007/s10973-006-7858-x text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-7858-x text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Legendre A. Instituto de Química de Araraquara, UNESP, C.P. 355, 14800-900, Araraquara, SP, Brazil aut NATIONALLICENCE 700 1- Correa J. Instituto de Química de Araraquara, UNESP, C.P. 355, 14800-900, Araraquara, SP, Brazil aut NATIONALLICENCE 700 1- Bannach G. Instituto de Química de Araraquara, UNESP, C.P. 355, 14800-900, Araraquara, SP, Brazil aut NATIONALLICENCE 700 1- Mauro A. Instituto de Química de Araraquara, UNESP, C.P. 355, 14800-900, Araraquara, SP, Brazil aut NATIONALLICENCE 700 1- Ionashiro M. Instituto de Química de Araraquara, UNESP, C.P. 355, 14800-900, Araraquara, SP, Brazil aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 87/3(2007-03-01), 779-782 1388-6150 87:3<779 2007 87 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer