caa a22 4500 463192931 CHVBK 20180406164914.0 cr unu---uuuuu 170326e20070301xx s 000 0 eng 10.1007/s10973-006-8203-0 doi (NATIONALLICENCE)springer-10.1007/s10973-006-8203-0 Thermalanalysis and structural characterization of Bi4V2-xBaxO11-1.5x (0.02≤ x ≤0.50) [Elektronische Daten] [L. Malta, Marta Medeiros] This work reports the study of Bi4V2-xBaxO11-1.5x (0.02≤x≤0.50) series, which is a potential source of solid electrolytes to apply in oxygen sensors. X-ray powder diffraction was used to point out the formation of major ionic conductive phases and minor ones. The modifications of vanadate substructure were probed, at short range, by Fourier-transform infrared spectroscopy. Differential scanning calorimetry evidenced the formation of tetragonal γ phase, which can be ionic conductive, for x=0.14. Springer-Verlag, 2007 BIMEVOX nationallicence order-disorder transition nationallicence solid electrolyte nationallicence Malta L. Department of Inorganic Chemistry, Institute of Chemistry, UFRJ, Cidade Universitária CT Bloco A-Lab. 638, 21945-970, Rio de Janeiro, RJ, Brazil aut Medeiros Marta Department of Inorganic Chemistry, Institute of Chemistry, UFRJ, Cidade Universitária CT Bloco A-Lab. 638, 21945-970, Rio de Janeiro, RJ, Brazil aut Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 87/3(2007-03-01), 883-886 1388-6150 87:3<883 2007 87 10973 https://doi.org/10.1007/s10973-006-8203-0 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-006-8203-0 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Malta L. Department of Inorganic Chemistry, Institute of Chemistry, UFRJ, Cidade Universitária CT Bloco A-Lab. 638, 21945-970, Rio de Janeiro, RJ, Brazil aut NATIONALLICENCE 700 1- Medeiros Marta Department of Inorganic Chemistry, Institute of Chemistry, UFRJ, Cidade Universitária CT Bloco A-Lab. 638, 21945-970, Rio de Janeiro, RJ, Brazil aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Kluwer Academic Publishers 87/3(2007-03-01), 883-886 1388-6150 87:3<883 2007 87 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer