caa a22 4500 463193563 CHVBK 20180406164915.0 cr unu---uuuuu 170326e20070101xx s 000 0 eng 10.1007/s10973-005-7472-3 doi (NATIONALLICENCE)springer-10.1007/s10973-005-7472-3 Benzamidespecies retained by DMSO composites at a kaolinite surface [Elektronische Daten] [B. Caglar, B. Afsin, A. Tabak] The surface area of kaolinite-benzamide (K-Bz) 6.62 m2 g-1, which is noticeably lower than that of kaolinite-dimethyl sulphoxide (K-DMSO) 14.61 m2 g-1, the co-perturbation of the inner-surface hydroxyl features at 3697 and 3650 cm-1, and the increase of d(001) value by 7.44 Å are all related to the benzamide species inserted into the kaolinite structure through the replacement of the K-DMSO composites. Disappearance of the DMSO reflections and emergence of well-defined features at 6.04(2θ) and 11.16(2θ), 001 and 002 reflections with d values of 14.62 and 7.92 Å, respectively point out that the DMSO species were substituted efficiently by benzamide molecules. The thermal stability of the K-Bz derivative up to 300°C can be attributed to the slightly tilted aromatic ring keying into the gibbsitic sheets via the -NH2 groups. Springer-Verlag, 2007 benzamide nationallicence DMSO nationallicence inner surface hydroxyls nationallicence kaolinite nationallicence preadsorption nationallicence Caglar B. Department of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayis University, 55139, Kurupelit, Samsun, Turkey aut Afsin B. Department of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayis University, 55139, Kurupelit, Samsun, Turkey aut Tabak A. Department of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayis University, 55139, Kurupelit, Samsun, Turkey aut Journal of Thermal Analysis and Calorimetry Springer Netherlands 87/2(2007-01-01), 429-432 1388-6150 87:2<429 2007 87 10973 https://doi.org/10.1007/s10973-005-7472-3 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10973-005-7472-3 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Caglar B. Department of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayis University, 55139, Kurupelit, Samsun, Turkey aut NATIONALLICENCE 700 1- Afsin B. Department of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayis University, 55139, Kurupelit, Samsun, Turkey aut NATIONALLICENCE 700 1- Tabak A. Department of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayis University, 55139, Kurupelit, Samsun, Turkey aut NATIONALLICENCE 773 0- Journal of Thermal Analysis and Calorimetry Springer Netherlands 87/2(2007-01-01), 429-432 1388-6150 87:2<429 2007 87 10973 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer