caa a22 4500 463214129 CHVBK 20180405153151.0 cr unu---uuuuu 170326e20070301xx s 000 0 eng 10.1007/s00339-006-3789-4 doi (NATIONALLICENCE)springer-10.1007/s00339-006-3789-4 Quantitative depth profile study of polyaniline films by photothermal spectroscopies [Elektronische Daten] [J.E. de Albuquerque, D.T. Balogh, R.M. Faria] In this study, we carried out a quantitative depth profile analysis of the optical properties of slightly and strongly doped polyaniline (PANI) films, using both photoacoustic and photopyroelectric spectroscopies. As the thermal diffusion length varies inversely to chopper modulation frequency, then at high chopping frequencies information about the sample near the surface is obtained, while at low chopping frequencies the data come from deeper within the sample. The objective of this study is to analyze how the polyaniline doping process in acidic media occurs in the polymeric chain using the photothermal techniques. The results showed that polymeric chains of the doped samples are composed of undoped regions, while polymeric chains of slightly doped samples present doped regions to a lesser degree. These conclusions are in accordance with published results in which doped PANI films exhibit a granular conductive regions in a quasi undoped matrix. In addition, the photothermal spectra showed that the doping process of PANI, in which films are dipped in hydrochloric acid solution, is more effective in the external surface of the films. Springer-Verlag, 2006 de Albuquerque J.E. Departamento de Física, Universidade Federal de Viçosa, 36571-000, Viçosa, MG, Brazil aut Balogh D.T. Instituto de Física de São Carlos/USP, 13560-970, São Carlos, SP, Brazil aut Faria R.M. Instituto de Física de São Carlos/USP, 13560-970, São Carlos, SP, Brazil aut Applied Physics A Springer-Verlag 86/3(2007-03-01), 395-401 0947-8396 86:3<395 2007 86 339 https://doi.org/10.1007/s00339-006-3789-4 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s00339-006-3789-4 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- de Albuquerque J.E. Departamento de Física, Universidade Federal de Viçosa, 36571-000, Viçosa, MG, Brazil aut NATIONALLICENCE 700 1- Balogh D.T. Instituto de Física de São Carlos/USP, 13560-970, São Carlos, SP, Brazil aut NATIONALLICENCE 700 1- Faria R.M. Instituto de Física de São Carlos/USP, 13560-970, São Carlos, SP, Brazil aut NATIONALLICENCE 773 0- Applied Physics A Springer-Verlag 86/3(2007-03-01), 395-401 0947-8396 86:3<395 2007 86 339 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer