caa a22 4500 463219406 CHVBK 20180405153207.0 cr unu---uuuuu 170326e20071201xx s 000 0 eng 10.1134/S1061934807120131 doi (NATIONALLICENCE)springer-10.1134/S1061934807120131 Potentials of gas chromatography in the determination of reaction products in the catalytic oxidation of ammonia to nitrogen(II) oxide [Elektronische Daten] [V. Zheivot, T. Nikoro, V. Krivoruchko, L. Panina, L. Pinaeva, L. Isupova] Peculiarities of the determination of nitrogen oxides and ammonia in the reaction products of ammonia oxidation are studied by gas chromatography. Particular attention was paid to the sampling problem. It is shown that in the course of the transportation of samples containing nitrogen(II) oxide and oxygen, the oxidation of nitrogen(II) oxide to nitrogen(IV) oxide takes place in the vapor phase. The conditions were found for suppressing or even eliminating the gas-phase reaction of NO oxidation to NO2. A procedure for the gas-chromatographic analysis of the reaction products in the catalytic oxidation of ammonia is proposed using several samples and packed columns, including the determination of NO with respect to NO2 formed in the gas-phase oxidation of NO. Pleiades Publishing, Ltd., 2007 Zheivot V. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 5, 630090, Novosibirsk, Russia aut Nikoro T. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 5, 630090, Novosibirsk, Russia aut Krivoruchko V. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 5, 630090, Novosibirsk, Russia aut Panina L. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 5, 630090, Novosibirsk, Russia aut Pinaeva L. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 5, 630090, Novosibirsk, Russia aut Isupova L. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 5, 630090, Novosibirsk, Russia aut Journal of Analytical Chemistry Nauka/Interperiodica 62/12(2007-12-01), 1170-1175 1061-9348 62:12<1170 2007 62 10809 https://doi.org/10.1134/S1061934807120131 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1134/S1061934807120131 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Zheivot V. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 5, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Nikoro T. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 5, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Krivoruchko V. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 5, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Panina L. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 5, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Pinaeva L. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 5, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Isupova L. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 5, 630090, Novosibirsk, Russia aut NATIONALLICENCE 773 0- Journal of Analytical Chemistry Nauka/Interperiodica 62/12(2007-12-01), 1170-1175 1061-9348 62:12<1170 2007 62 10809 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer