caa a22 4500 463222172 CHVBK 20180405153215.0 cr unu---uuuuu 170326e20070801xx s 000 0 eng 10.1007/s10853-006-1329-4 doi (NATIONALLICENCE)springer-10.1007/s10853-006-1329-4 Preparation of inorganic-organic pillared montmorillonite using ultrasonic treatment [Elektronische Daten] [Huiming Guo, Xiaoyan Jing, Lulu Zhang, Jun Wang] Montmorillonite (Mt) is a clay mineral with expandable layer structure. Mesoporous pillared montmorillonite can be prepared by introducing gallery templates, such as simple metal cations, quaternary ammonium cations, long chain amines, and hydroxyed inorganic metal ions. In this paper, inorganic-organic pillared montmorillonite intercalated by aluminium and alkyl ammonium chloridize (HDTMA-Cl) was successfully prepared by ultrasonic treatment, and the physicochemical properties of the materials were systematically characterized by XRD, FT-IR, SEM and TEM techniques. The d001 basal spacings and microstructures of Mt-Al-HDTMA were characterized by XRD. The function group, crystal surface morphology, structural and chemical analysis of Mt-Al-HDTMA were measured by FT-IR, SEM, TEM and EDX. The results indicated that ultrasonic method might accelerate the diffusion of the intercalating species, which enhanced the textural properties and the morphologies. The results also suggested that aluminium and HDTMA-Cl reagent entered the interlayer of Mt, and that the crystal structure of the final Mt was preserved. Springer Science+Business Media, LLC, 2007 Guo Huiming School of Materials Science and Chemical Engineering, Harbin Engineering University, 150001, Harbin, P.R. China aut Jing Xiaoyan School of Materials Science and Chemical Engineering, Harbin Engineering University, 150001, Harbin, P.R. China aut Zhang Lulu School of Materials Science and Chemical Engineering, Harbin Engineering University, 150001, Harbin, P.R. China aut Wang Jun School of Materials Science and Chemical Engineering, Harbin Engineering University, 150001, Harbin, P.R. China aut Journal of Materials Science Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 42/16(2007-08-01), 6951-6955 0022-2461 42:16<6951 2007 42 10853 https://doi.org/10.1007/s10853-006-1329-4 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10853-006-1329-4 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Guo Huiming School of Materials Science and Chemical Engineering, Harbin Engineering University, 150001, Harbin, P.R. China aut NATIONALLICENCE 700 1- Jing Xiaoyan School of Materials Science and Chemical Engineering, Harbin Engineering University, 150001, Harbin, P.R. China aut NATIONALLICENCE 700 1- Zhang Lulu School of Materials Science and Chemical Engineering, Harbin Engineering University, 150001, Harbin, P.R. China aut NATIONALLICENCE 700 1- Wang Jun School of Materials Science and Chemical Engineering, Harbin Engineering University, 150001, Harbin, P.R. China aut NATIONALLICENCE 773 0- Journal of Materials Science Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 42/16(2007-08-01), 6951-6955 0022-2461 42:16<6951 2007 42 10853 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer