caa a22 4500 463222539 CHVBK 20180405153216.0 cr unu---uuuuu 170326e20071001xx s 000 0 eng 10.1007/s10853-007-1728-1 doi (NATIONALLICENCE)springer-10.1007/s10853-007-1728-1 In situ SALS and volume variation measurements during deformation of treated silica filled SBR [Elektronische Daten] [J. Ramier, L. Chazeau, C. Gauthier, L. Stelandre, L. Guy, E. Peuvrel-Disdier] Original in situ measurements of volume variation and small angle light scattering (SALS) are performed on silica filled Styrene Butadiene Rubber (SBR) during tensile tests. The influence of the silica treatment on the mechanisms involved is explored with sample carefully characterised and with the same filler dispersion. Two different types of silane are used as treatment, an alkoxy silane (so called covering agent) and a coupling agent which enables covalent bonds between the silica and the polymer matrix. It is shown that the coupling agent delays void formation in the samples and leads at intermediary strain to the reorganisation of the filler structure while the covering agent eases the void formation which also occurs without silica surface treatment. Springer Science+Business Media, LLC, 2007 Ramier J. MATEIS (UMR CNRS 5510), INSA-Lyon, 69621, Villeurbanne Cedex, France aut Chazeau L. MATEIS (UMR CNRS 5510), INSA-Lyon, 69621, Villeurbanne Cedex, France aut Gauthier C. MATEIS (UMR CNRS 5510), INSA-Lyon, 69621, Villeurbanne Cedex, France aut Stelandre L. Rhodia Silices, 15 Rue Pierre Pays, B.P. 52, 69660, Collonges au Mont d'or, France aut Guy L. Rhodia Silices, 15 Rue Pierre Pays, B.P. 52, 69660, Collonges au Mont d'or, France aut Peuvrel-Disdier E. Ecole des Mines de Paris, Centre de Mise en Forme des Matériaux, 1, Rue Claude Daunesse, 06904, Sophia Antipolis Cedex, France aut Journal of Materials Science Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 42/19(2007-10-01), 8130-8138 0022-2461 42:19<8130 2007 42 10853 https://doi.org/10.1007/s10853-007-1728-1 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10853-007-1728-1 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ramier J. MATEIS (UMR CNRS 5510), INSA-Lyon, 69621, Villeurbanne Cedex, France aut NATIONALLICENCE 700 1- Chazeau L. MATEIS (UMR CNRS 5510), INSA-Lyon, 69621, Villeurbanne Cedex, France aut NATIONALLICENCE 700 1- Gauthier C. MATEIS (UMR CNRS 5510), INSA-Lyon, 69621, Villeurbanne Cedex, France aut NATIONALLICENCE 700 1- Stelandre L. Rhodia Silices, 15 Rue Pierre Pays, B.P. 52, 69660, Collonges au Mont d'or, France aut NATIONALLICENCE 700 1- Guy L. Rhodia Silices, 15 Rue Pierre Pays, B.P. 52, 69660, Collonges au Mont d'or, France aut NATIONALLICENCE 700 1- Peuvrel-Disdier E. Ecole des Mines de Paris, Centre de Mise en Forme des Matériaux, 1, Rue Claude Daunesse, 06904, Sophia Antipolis Cedex, France aut NATIONALLICENCE 773 0- Journal of Materials Science Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 42/19(2007-10-01), 8130-8138 0022-2461 42:19<8130 2007 42 10853 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer