caa a22 4500 46322647X CHVBK 20180405153228.0 cr unu---uuuuu 170326e20070901xx s 000 0 eng 10.1007/s10853-007-1686-7 doi (NATIONALLICENCE)springer-10.1007/s10853-007-1686-7 Preparation and characterization of ionic liquid intercalation compounds into layered zirconium phosphates [Elektronische Daten] [Haiyan Wang, Mingjian Zou, Na Li, Kean Li] In this work, immobilizing a series of ionic liquids (ILs) 1-alkyl-3-methylimidazolium chloride [C n mim]Cl (n=2, 4, 6, 8) on the layered zirconium phosphates were investigated. [C4mim]Cl was used to explore in detail the factors affecting intercalation. By comparing several starting materials including α-zirconium phosphate (α-ZrP), γ-zirconium phosphate (γ-ZrP) and the corresponding alkylamine preintercalated composites, it was found that the α-ZrP·2BA (i.e., preintercalated BA were arranged in a bilayer mode at the galleries of α-ZrP) was a suitable host for intercalating ILs. Intercalation was verified with X-ray diffraction (XRD), Raman, UV-Vis and other instrumental approaches. pH effect on immobilization was investigated. Other ionic liquids including [C n mim]Cl (n=2, 6, 8) intercalation compounds were prepared. Based on XRD data, the interlayer distances of the studied intercalation compounds were similar, suggesting that the ionic liquids were arranged in an approximately planar manner, as confirmed by molecular modeling. Springer Science+Business Media, LLC, 2007 Wang Haiyan The Key Laboratory of Global Change and Marine-Atmospheric Chemistry, Third Institute of Oceanography of State Oceanic Administration, 361005, Xiamen, China aut Zou Mingjian College of Chemistry and Molecular Engineering, Peking University, 100871, Beijing, China aut Li Na College of Chemistry and Molecular Engineering, Peking University, 100871, Beijing, China aut Li Kean College of Chemistry and Molecular Engineering, Peking University, 100871, Beijing, China aut Journal of Materials Science Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 42/18(2007-09-01), 7738-7744 0022-2461 42:18<7738 2007 42 10853 https://doi.org/10.1007/s10853-007-1686-7 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10853-007-1686-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wang Haiyan The Key Laboratory of Global Change and Marine-Atmospheric Chemistry, Third Institute of Oceanography of State Oceanic Administration, 361005, Xiamen, China aut NATIONALLICENCE 700 1- Zou Mingjian College of Chemistry and Molecular Engineering, Peking University, 100871, Beijing, China aut NATIONALLICENCE 700 1- Li Na College of Chemistry and Molecular Engineering, Peking University, 100871, Beijing, China aut NATIONALLICENCE 700 1- Li Kean College of Chemistry and Molecular Engineering, Peking University, 100871, Beijing, China aut NATIONALLICENCE 773 0- Journal of Materials Science Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 42/18(2007-09-01), 7738-7744 0022-2461 42:18<7738 2007 42 10853 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer