caa a22 4500 463227573 CHVBK 20180405153231.0 cr unu---uuuuu 170326e20070501xx s 000 0 eng 10.1007/s10853-006-0570-1 doi (NATIONALLICENCE)springer-10.1007/s10853-006-0570-1 Effects of morphology and cesium promotion over silver nanoparticles catalysts in the styrene epoxidation [Elektronische Daten] [Ricardo Chimentao, Francesc Medina, Jesús Sueiras, José Fierro, Yolanda Cesteros, Pilar Salagre] Silver nanowires have been obtained by polyol reduction of silver nitrate in presence of polyvinyl-pyrrolidone (PVP). The as-synthesized silver nanowires were deposited on α-Al2O3. For comparison silver catalysts were also prepared by wetness impregnation obtaining irregularly shaped silver particles. Epoxidation of styrene to styrene oxide (SO) by molecular oxygen was studied using the silver catalysts. The main products were styrene oxide (SO) and phenylacetaldehyde (Phe). The promotion effect of the Cs on the silver nanowires catalysts was investigated. The Cs loading was in the range of 0-1wt.% (refereed to silver). Furthermore, the effect of O2:C8H8 molar ratio on the catalytic epoxidation was also investigated. Silver nanowires catalysts showed superior catalytic activity compared to those prepared by impregnation method. Besides, higher O2:C8H8 ratios improved the selectivity to SO. The catalytic activity showed a maximum performance for silver nanowires promoted with 0.25wt.% of Cs, achieving 94.6% of conversion and total selectivity to desired oxidation products (styrene oxide and phenylacetaldehyde). Moreover, the cesium promotion also contributed to the increase in the selectivity to styrene oxide. Temperature programmed reduction (TPR) and X-ray photoelectron spectroscopy (XPS) were employed to detect the presence of different species of oxygen in the catalysts indicating that subsurface oxygen was beneficial for the epoxidation. The samples were also structurally characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-visible absorption spectra and selected area electron diffraction pattern (SAED). Springer Science+Business Media, LLC, 2007 Chimentao Ricardo Dept. d'Enginyeria Química, Universitat Rovira i Virgili, 43007, Tarragona, Spain aut Medina Francesc Dept. d'Enginyeria Química, Universitat Rovira i Virgili, 43007, Tarragona, Spain aut Sueiras Jesús Dept. d'Enginyeria Química, Universitat Rovira i Virgili, 43007, Tarragona, Spain aut Fierro José Instituto de Catalisis y Petroleoquimica, CSIC, 28049, Cantoblanco, Madrid, Spain aut Cesteros Yolanda Dept. de Química Inorgánica, Universitat Rovira i Virgili, 43007, Tarragona, Spain aut Salagre Pilar Dept. de Química Inorgánica, Universitat Rovira i Virgili, 43007, Tarragona, Spain aut Journal of Materials Science Springer US; http://www.springer-ny.com 42/10(2007-05-01), 3307-3314 0022-2461 42:10<3307 2007 42 10853 https://doi.org/10.1007/s10853-006-0570-1 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10853-006-0570-1 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Chimentao Ricardo Dept. d'Enginyeria Química, Universitat Rovira i Virgili, 43007, Tarragona, Spain aut NATIONALLICENCE 700 1- Medina Francesc Dept. d'Enginyeria Química, Universitat Rovira i Virgili, 43007, Tarragona, Spain aut NATIONALLICENCE 700 1- Sueiras Jesús Dept. d'Enginyeria Química, Universitat Rovira i Virgili, 43007, Tarragona, Spain aut NATIONALLICENCE 700 1- Fierro José Instituto de Catalisis y Petroleoquimica, CSIC, 28049, Cantoblanco, Madrid, Spain aut NATIONALLICENCE 700 1- Cesteros Yolanda Dept. de Química Inorgánica, Universitat Rovira i Virgili, 43007, Tarragona, Spain aut NATIONALLICENCE 700 1- Salagre Pilar Dept. de Química Inorgánica, Universitat Rovira i Virgili, 43007, Tarragona, Spain aut NATIONALLICENCE 773 0- Journal of Materials Science Springer US; http://www.springer-ny.com 42/10(2007-05-01), 3307-3314 0022-2461 42:10<3307 2007 42 10853 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer