caa a22 4500 463228022 CHVBK 20180405153233.0 cr unu---uuuuu 170326e20071201xx s 000 0 eng 10.1007/s10853-007-1634-6 doi (NATIONALLICENCE)springer-10.1007/s10853-007-1634-6 Synthesis and applications of fluoroalkyl end-capped cooligomers having fullerene and mixed fullerenes in the main chain [Elektronische Daten] [Remi Kasai, Hideaki Yaegashi, Hiroshi Yokoyama, Masahiko Yamanaka, Hideo Sawada] Fluoroalkanoyl peroxides reacted with FULLERENES [fullerene (C60) and commercially available fullerenes (Nanom MixTR and Nanom BlackTR)] and radical polymerizable comonomers such as acrylic acid, N,N-dimethylacrylamide, N-(1,1-dimethyl-3-oxobutyl)acrylamide, and acryloylmorpholine to afford fluoroalkyl end-capped cooligomers having FULLERENES in the main chain under very mild conditions. Fluoroalkyl end-capped Nanom Mix and Nanom Black cooligomers thus obtained were found to exhibit a similar solubility to that of the corresponding fluoroalkyl end-capped cooligomers having fullerene in the main chain. These fluorinated FULLERENES cooligomers were found to form the nanometer size-controlled self-assembled cooligomeric aggregates in aqueous solutions. These fluoroalkyl end-capped FULLERENES cooligomers were more effective for solubilizing fullerene, Nanom Mix and Nanom Black into water, compared to those of the corresponding fluoroalkyl end-capped homooligomers having no FULLERENES in the main chain. Fluoroalkyl end-capped fullerene- and Nanom Mix-acrylic acid cooligomers were found to exhibit fluorescence spectra related to fullerene and Nanom Mix in cooligomers, respectively, in aqueous solutions. Additionally, these fluorinated fullerene- and Nanom Mix-acrylic acid cooligomers were able to increase chemiluminescence intensity related to luminol, effectively, compared to the corresponding fluorinated acrylic acid homooligomers. Springer Science+Business Media, LLC, 2007 Kasai Remi Department of Frontier Materials Chemistry, Faculty of Science and Technology, Hirosaki University, 036-8561, Bunkyo-cho, Hirosaki, Japan aut Yaegashi Hideaki Technology Development Division, Nissan Motor Co., Ltd, 243-0192, Atsugi-shi, Kanagawa, Japan aut Yokoyama Hiroshi Technology Development Division, Nissan Motor Co., Ltd, 243-0192, Atsugi-shi, Kanagawa, Japan aut Yamanaka Masahiko Technology Development Division, Nissan Motor Co., Ltd, 243-0192, Atsugi-shi, Kanagawa, Japan aut Sawada Hideo Department of Frontier Materials Chemistry, Faculty of Science and Technology, Hirosaki University, 036-8561, Bunkyo-cho, Hirosaki, Japan aut Journal of Materials Science Springer US; http://www.springer-ny.com 42/24(2007-12-01), 10228-10238 0022-2461 42:24<10228 2007 42 10853 https://doi.org/10.1007/s10853-007-1634-6 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10853-007-1634-6 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kasai Remi Department of Frontier Materials Chemistry, Faculty of Science and Technology, Hirosaki University, 036-8561, Bunkyo-cho, Hirosaki, Japan aut NATIONALLICENCE 700 1- Yaegashi Hideaki Technology Development Division, Nissan Motor Co., Ltd, 243-0192, Atsugi-shi, Kanagawa, Japan aut NATIONALLICENCE 700 1- Yokoyama Hiroshi Technology Development Division, Nissan Motor Co., Ltd, 243-0192, Atsugi-shi, Kanagawa, Japan aut NATIONALLICENCE 700 1- Yamanaka Masahiko Technology Development Division, Nissan Motor Co., Ltd, 243-0192, Atsugi-shi, Kanagawa, Japan aut NATIONALLICENCE 700 1- Sawada Hideo Department of Frontier Materials Chemistry, Faculty of Science and Technology, Hirosaki University, 036-8561, Bunkyo-cho, Hirosaki, Japan aut NATIONALLICENCE 773 0- Journal of Materials Science Springer US; http://www.springer-ny.com 42/24(2007-12-01), 10228-10238 0022-2461 42:24<10228 2007 42 10853 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer