caa a22 4500 463228871 CHVBK 20180405153235.0 cr unu---uuuuu 170326e20070901xx s 000 0 eng 10.1007/s10853-007-1553-6 doi (NATIONALLICENCE)springer-10.1007/s10853-007-1553-6 Controllable synthesis of ZnS holely microspheres in solution containing ethylenediamine and CS2 [Elektronische Daten] [Li Lingang, Tang Yu] ZnS holey microspheres (HMSs) were prepared by reacting ZnSO4 with sulfide source from CS2 and ethylenediamine at 50°C, then aging at room temperature. The synthesized HMSs were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and UV-visible absorption measurement. The results showed that the holes were formed by gas of H2S, and the small ZnS HMSs were formed by particles reaggregating with the aid of ethylenediamine. In addition, the size- and shape-controlled synthesis of ZnS HMSs was achieved by varying the process parameters, such as the aging time of the final solution, the molar ratio of CS2 and ethylenediamine, and so on. A gas obtruding mechanism was proposed. Springer Science+Business Media, LLC, 2007 Lingang Li Department of Chemistry and Life Science, West Anhui University, 237012, Luan, P.R. China aut Yu Tang Department of Chemistry, Jinan University, 510632, Guangzhou, P.R. China aut Journal of Materials Science Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 42/17(2007-09-01), 7245-7250 0022-2461 42:17<7245 2007 42 10853 https://doi.org/10.1007/s10853-007-1553-6 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10853-007-1553-6 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Lingang Li Department of Chemistry and Life Science, West Anhui University, 237012, Luan, P.R. China aut NATIONALLICENCE 700 1- Yu Tang Department of Chemistry, Jinan University, 510632, Guangzhou, P.R. China aut NATIONALLICENCE 773 0- Journal of Materials Science Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 42/17(2007-09-01), 7245-7250 0022-2461 42:17<7245 2007 42 10853 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer