caa a22 4500 463230000 CHVBK 20180405153239.0 cr unu---uuuuu 170326e20070201xx s 000 0 eng 10.1007/s10853-006-1433-5 doi (NATIONALLICENCE)springer-10.1007/s10853-006-1433-5 Mechanical and thermal properties of poly(arylene disulfide) derived from cyclic(4,4′-oxybis(benzene)disulfide) via ring-opening polymerization [Elektronische Daten] [L. Song, M. Xiao, D. Shu, S. Wang, Y. Meng] Mechanical and thermal properties of poly(arylene disulfide) synthesized by ring-opening reaction of cyclic(aromatic disulfide) oligomer were reported. These oligomers were prepared from 4,4′-oxybis(benzenethiol). Three-point bending tests were performed to measure the flexural properties of the poly(arylene disulfide). DSC and TGA techniques were used to characterize the thermal properties of these polymers. Ring-opening reactions were carried out by hot-press under atmosphere and nitrogen atmosphere, respectively. Oxidation reaction of these polymers was detected from Raman spectra under atmosphere. The glass transition temperature increased but 10% weight loss temperature decreased with increasing ring-opening temperature. The flexural strength decreased with increasing the temperature of ring-opening polymerization under both atmosphere and nitrogen atmosphere. The polydisulfides could be used as high temperature and thermally curing insulating materials to substitute epoxy resins. Springer Science+Business Media, LLC, 2007 Song L. School of Materials Sciences and Energy, Guangdong University of Technology, 5100006, Guangzhou, P.R. China aut Xiao M. State Key Laboratory of Optoelectronic Materials and Technologies/Institute of Optoelectronic and Functional Composite Materials, Sun Yat-Sen University, 510275, Guangzhou, P.R. China aut Shu D. State Key Laboratory of Optoelectronic Materials and Technologies/Institute of Optoelectronic and Functional Composite Materials, Sun Yat-Sen University, 510275, Guangzhou, P.R. China aut Wang S. State Key Laboratory of Optoelectronic Materials and Technologies/Institute of Optoelectronic and Functional Composite Materials, Sun Yat-Sen University, 510275, Guangzhou, P.R. China aut Meng Y. State Key Laboratory of Optoelectronic Materials and Technologies/Institute of Optoelectronic and Functional Composite Materials, Sun Yat-Sen University, 510275, Guangzhou, P.R. China aut Journal of Materials Science Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 42/4(2007-02-01), 1156-1161 0022-2461 42:4<1156 2007 42 10853 https://doi.org/10.1007/s10853-006-1433-5 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10853-006-1433-5 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Song L. School of Materials Sciences and Energy, Guangdong University of Technology, 5100006, Guangzhou, P.R. China aut NATIONALLICENCE 700 1- Xiao M. State Key Laboratory of Optoelectronic Materials and Technologies/Institute of Optoelectronic and Functional Composite Materials, Sun Yat-Sen University, 510275, Guangzhou, P.R. China aut NATIONALLICENCE 700 1- Shu D. State Key Laboratory of Optoelectronic Materials and Technologies/Institute of Optoelectronic and Functional Composite Materials, Sun Yat-Sen University, 510275, Guangzhou, P.R. China aut NATIONALLICENCE 700 1- Wang S. State Key Laboratory of Optoelectronic Materials and Technologies/Institute of Optoelectronic and Functional Composite Materials, Sun Yat-Sen University, 510275, Guangzhou, P.R. China aut NATIONALLICENCE 700 1- Meng Y. State Key Laboratory of Optoelectronic Materials and Technologies/Institute of Optoelectronic and Functional Composite Materials, Sun Yat-Sen University, 510275, Guangzhou, P.R. China aut NATIONALLICENCE 773 0- Journal of Materials Science Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 42/4(2007-02-01), 1156-1161 0022-2461 42:4<1156 2007 42 10853 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer