caa a22 4500 463232704 CHVBK 20180405153247.0 cr unu---uuuuu 170326e20070701xx s 000 0 eng 10.1007/s10853-006-0539-0 doi (NATIONALLICENCE)springer-10.1007/s10853-006-0539-0 Synthesis and selected properties of CrSbVO6 and phase relations in the V2O5-Cr2O3-α-Sb2O4 system in the solid state [Elektronische Daten] [Elżbieta Filipek, Grażyna Dąbrowska] Phase relations in the ternary oxide system V2O5-Cr2O3-α-Sb2O4 in the solid state in the atmosphere of air have been investigated by using the XRD, DTA/TG and IRS methods. Obtained results have shown that in the system the compound CrSbVO6 is formed. This compound has been obtained both from oxides and from a mixture comprising CrSbO4, CrVO4 and SbVO5 as well as from mixtures: CrSbO4/V2O5, CrVO4/α-Sb2O4 and SbVO5/Cr2O3. A Solid product of incongruent melting of CrSbVO6 at ∼1300°C is Cr2O3. CrSbVO6 crystallizes in the tetragonal system and its calculated unit cell parameters amount to: a=b=0.45719(12)nm, c=0.30282(8)nm, Z=2. The obtained results have allowed us also to divide the investigated system V2O5-Cr2O3-α-Sb2O4 into seven subsidiary subsystems and to determine temperatures and components concentration range in which CrSbVO6 remains at equilibrium in the solid state with other phases formed in corresponding binary systems. Springer Science+Business Media, LLC, 2007 Filipek Elżbieta Department of Inorganic and Analytical Chemistry, Szczecin University of Technology, Al. Piastow 42, 71-065, Szczecin, Poland aut Dąbrowska Grażyna Department of Inorganic and Analytical Chemistry, Szczecin University of Technology, Al. Piastow 42, 71-065, Szczecin, Poland aut Journal of Materials Science Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 42/13(2007-07-01), 4905-4915 0022-2461 42:13<4905 2007 42 10853 https://doi.org/10.1007/s10853-006-0539-0 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10853-006-0539-0 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Filipek Elżbieta Department of Inorganic and Analytical Chemistry, Szczecin University of Technology, Al. Piastow 42, 71-065, Szczecin, Poland aut NATIONALLICENCE 700 1- Dąbrowska Grażyna Department of Inorganic and Analytical Chemistry, Szczecin University of Technology, Al. Piastow 42, 71-065, Szczecin, Poland aut NATIONALLICENCE 773 0- Journal of Materials Science Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 42/13(2007-07-01), 4905-4915 0022-2461 42:13<4905 2007 42 10853 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer