caa a22 4500 463233247 CHVBK 20180405153248.0 cr unu---uuuuu 170326e20070701xx s 000 0 eng 10.1007/s10853-006-1268-0 doi (NATIONALLICENCE)springer-10.1007/s10853-006-1268-0 Correlating yield response with molecular architecture in polymer glasses [Elektronische Daten] [Kevin Calzia, Alan Lesser] The yield response of nine architecturally different glassy networks is investigated under several stress states, strain rates, and temperatures, and correlations are made among them. Differences in molecular architecture are quantified through two proposed governing parameters; the glass transition temperature, T g, capturing network stiffness and the cohesive energy density, E c, reflecting network strength. Cohesive energy density is estimated using molecular modeling techniques and supported by solvent swelling experiments. The limits of the correlations made between molecular architecture and yield behavior are further studied with attempts to relate yielding in thermoplastic glasses and heterogeneous networks. Springer Science+Business Media, LLC, 2006 Calzia Kevin Polymer Science and Engineering Department, University of Massachusetts Amherst, 120 Governors Dr, 01003, Amherst, MA, USA aut Lesser Alan Polymer Science and Engineering Department, University of Massachusetts Amherst, 120 Governors Dr, 01003, Amherst, MA, USA aut Journal of Materials Science Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 42/13(2007-07-01), 5229-5238 0022-2461 42:13<5229 2007 42 10853 https://doi.org/10.1007/s10853-006-1268-0 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10853-006-1268-0 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Calzia Kevin Polymer Science and Engineering Department, University of Massachusetts Amherst, 120 Governors Dr, 01003, Amherst, MA, USA aut NATIONALLICENCE 700 1- Lesser Alan Polymer Science and Engineering Department, University of Massachusetts Amherst, 120 Governors Dr, 01003, Amherst, MA, USA aut NATIONALLICENCE 773 0- Journal of Materials Science Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 42/13(2007-07-01), 5229-5238 0022-2461 42:13<5229 2007 42 10853 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer