caa a22 4500 463233484 CHVBK 20180405153249.0 cr unu---uuuuu 170326e20070601xx s 000 0 eng 10.1007/s10853-006-1345-4 doi (NATIONALLICENCE)springer-10.1007/s10853-006-1345-4 Gibbs energy calculation of liquid Zr-Al-Ni and Zr-Al-Cu-Ni alloys with clusters [Elektronische Daten] [H. Li, Y. Yang, W. Tong, Z. Wang] The Gibbs energies of liquid Zr-Al-Ni and Zr-Al-Ni-Cu alloys with multi-clusters are calculated based on the statistical mechanism in this paper. The results show that the quantity of clusters depends mainly on the temperature and the concentration of the melt. It increases gradually with the decrease of temperature or with the increase of x Ni in liquid (Zr80Al20)1−x Ni x alloys; the quantity of Zr2Ni clusters reaches its maximum of 0.061mole at x Ni=0.336. In (Zr80Al20)1−x Ni x liquid alloy the existence of clusters causes the falling of the Gibbs energy. The Gibbs energy drops about 4000J/mol at x Ni=0.35 if the effect of cluster of Zr2Ni is considered or about 8000J/mol at x Ni=0.40 if both of clusters of Zr2Ni and ZrNi are taken into account. Springer Science+Business Media, LLC, 2007 Li H. Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, 110016, Shenyang, China aut Yang Y. Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, 110016, Shenyang, China aut Tong W. Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, 110016, Shenyang, China aut Wang Z. Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, 110016, Shenyang, China aut Journal of Materials Science Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 42/11(2007-06-01), 4060-4065 0022-2461 42:11<4060 2007 42 10853 https://doi.org/10.1007/s10853-006-1345-4 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10853-006-1345-4 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Li H. Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, 110016, Shenyang, China aut NATIONALLICENCE 700 1- Yang Y. Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, 110016, Shenyang, China aut NATIONALLICENCE 700 1- Tong W. Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, 110016, Shenyang, China aut NATIONALLICENCE 700 1- Wang Z. Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, 110016, Shenyang, China aut NATIONALLICENCE 773 0- Journal of Materials Science Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 42/11(2007-06-01), 4060-4065 0022-2461 42:11<4060 2007 42 10853 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer